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Oxidation of rock-derived, petrogenic, organic carbon (OC petro ) during weathering of sedimentary rocks is a major source of carbon dioxide (CO 2 ) to the atmosphere. This geological respiration is thought to be enhanced by physical erosion, suggesting that mountain belts could release large amounts of CO 2 to counter the CO 2 sequestration achieved by the erosion, riverine transfer and oceanic burial of organic carbon from the terrestrial biosphere. However, OC petro oxidation rates in mountain belts have not been quantified. Here we use rhenium (Re) as a proxy to track OC petro oxidation in mountain river catchments of Taiwan, where existing measurements of physical erosion rate allow the controls on OC petro oxidation to be assessed. Re has been shown to be closely associated with OC petro in rocks and following oxidation during chemical weathering forms a soluble oxyanion ( ReO 4 − ) which contributes to the dissolved load of rivers. Soils on meta-sedimentary rocks in Taiwan show that Re loss is coupled to OC petro loss during weathering, confirming previous observations from soil profiles on sedimentary rocks elsewhere. In Taiwan rivers, dissolved Re flux increases with the catchment-average sediment yield, suggesting that physical erosion rate is a major control on OC petro oxidation. Based on our current understanding of Re mobility during weathering, the dissolved Re flux can be used to quantify an upper bound on the OC petro oxidation rate and the associated CO 2 transfer. The estimated CO 2 release from this mountain belt by OC petro oxidation does not negate estimates of CO 2 sequestration by burial of biospheric OC offshore. The findings are compared to OC transfers estimated for the Himalaya, where OC petro oxidation in the mountain belt remains unconstrained. Together, these cases suggest that mountain building in the tropics can result in a net sink of OC which sequesters atmospheric CO 2 . [ABSTRACT FROM AUTHOR]

• 0.3‰ of δ 187 Re variation across rivers from the Mackenzie River basin. • For each river, the δ 187 Re of the dissolved load is higher than that of the corresponding river sediment • The δ 187 Re of river water and sediments is controlled by both provenance and modern oxidative weathering processes • The average δ 187 Re of Mackenzie bedrock (∼ − 0.05 ‰) and dissolved load (∼ − 0.01 ‰) are lower than Atlantic seawater δ 187 Re. Rhenium (Re) is a trace element whose redox chemistry makes it an ideal candidate to trace a range of geochemical processes. Here, we report the first rhenium isotopic measurements (δ 187 Re) from river-borne materials to assess the influence of chemical weathering on Re isotopes at continental scale. The δ 187 Re was measured in water, suspended sediments and bedloads from the Mackenzie River and its main Arctic tributaries in Northwestern Canada. We find that the δ 187 Re (relative to NIST SRM 989) of river waters ranges from −0.05‰ to +0.07‰, which is generally higher than the corresponding river sediment (−0.25‰ to +0.01‰). We show that the range of δ 187 Re in river sediments (∼0.30‰) is controlled by a combination of source bedrock isotopic variability (provenance) and modern oxidative weathering processes. After correcting for bedrock variability, the δ 187 Re of solids appear to be positively correlated with the amount of Re depletion related to oxidative weathering. This correlation, and the offset in δ 187 Re between river water and sediment, can be explained by preferential oxidation of reactive phases with high δ 187 Re (i.e. rock organic carbon, sulfide minerals), but could also result from fractionation during oxidation or the influence of secondary weathering processes. Overall, we find that both basin-average bedrock δ 187 Re (∼−0.05‰) and dissolved δ 187 Re (∼−0.01‰) in the Mackenzie River are lower than the δ 187 Re of Atlantic seawater (+0.12‰). These observations provide impetus for future work to constrain the Re isotope mass balance of seawater, and assess the potential for secular shifts in its δ 187 Re values over time, which could provide an additional isotopic proxy to trace current and past redox processes at Earth's Surface. [ABSTRACT FROM AUTHOR]

Earthquakes cause widespread landslides that can increase erosional fluxes observed over years to decades. However, the impact of earthquakes on denudation over the longer timescales relevant to orogenic evolution remains elusive. Here we assess erosion associated with earthquake-triggered landslides in the Longmen Shan range at the eastern margin of the Tibetan Plateau. We use the M w 7.9 2008 Wenchuan and M w 6.6 2013 Lushan earthquakes to evaluate how seismicity contributes to the erosional budget from short timescales (annual to decadal, as recorded by sediment fluxes) to long timescales (kyr to Myr, from cosmogenic nuclides and low temperature thermochronology). Over this wide range of timescales, the highest rates of denudation in the Longmen Shan coincide spatially with the region of most intense landsliding during the Wenchuan earthquake. Across sixteen gauged river catchments, sediment flux-derived denudation rates following the Wenchuan earthquake are closely correlated with seismic ground motion and the associated volume of Wenchuan-triggered landslides ( r 2 > 0.6 ), and to a lesser extent with the frequency of high intensity runoff events ( r 2 = 0.36 ). To assess whether earthquake-induced landsliding can contribute importantly to denudation over longer timescales, we model the total volume of landslides triggered by earthquakes of various magnitudes over multiple earthquake cycles. We combine models that predict the volumes of landslides triggered by earthquakes, calibrated against the Wenchuan and Lushan events, with an earthquake magnitude–frequency distribution. The long-term, landslide-sustained “seismic erosion rate” is similar in magnitude to regional long-term denudation rates (∼0.5–1 mm yr −1 ). The similar magnitude and spatial coincidence suggest that earthquake-triggered landslides are a primary mechanism of long-term denudation in the frontal Longmen Shan. We propose that the location and intensity of seismogenic faulting can contribute to focused denudation along a high-relief plateau margin. [ABSTRACT FROM AUTHOR]

The erosion of major mountain ranges is thought to be largely cannibalistic, recycling sediments that were deposited in the ocean or on the continents prior to mountain uplift. Despite this recognition, it has not yet been possible to quantify the amount of recycled material that is presently transported by rivers to the ocean. Here, we have analyzed the Li content and isotope composition (δ7Li) of suspended sediments sampled along river depth profiles and bed sands in three of the largest Earth's river systems (Amazon, Mackenzie and Ganga-Brahmaputra rivers). The δ7Li values of river-sediments transported by these rivers range from +5.3 to -3.6‰ and decrease with sediment grain size. We interpret these variations as reflecting a mixture of unweathered rock fragments (preferentially transported at depth in the coarse fraction) and present-day weathering products (preferentially transported at the surface in the finest fraction). Only the finest surface sediments contain the complementary reservoir of Li solubilized by water-rock interactions within the watersheds. Li isotopes also show that river bed sands can be interpreted as a mixture between unweathered fragments of igneous and sedimentary rocks. A mass budget approach, based on Li isotopes, Li/Al and Na/Al ratios, solved by an inverse method allows us to estimate that, for the large rivers analyzed here, the part of solid weathering products formed by present-day weathering reactions and transported to the ocean do not exceed 35%. Li isotopes also show that the sediments transported by the Amazon, Mackenzie and Ganga-Brahmaputra river systems are mostly sourced from sedimentary rocks (>60%) rather than igneous rocks. This study shows that Li isotopes in the river particulate load are a good proxy for quantifying both the erosional rock sources and the fingerprint of present-day weathering processes. Overall, Li isotopes in river sediments confirm the cannibalistic nature of erosion and weathering. [ABSTRACT FROM AUTHOR]

Abstract: The concentration of 10Be in detrital quartz (10Beqtz) from river sediments is now widely used to quantify catchment-wide denudation rates but may also be sensitive to inputs from bedrock landslides that deliver sediment with low 10Beqtz. Major landslide-triggering events can provide large amounts of low-concentration material to rivers in mountain catchments, but changes in river sediment 10Beqtz due to such events have not yet been measured directly. Here we examine the impact of widespread landslides triggered by the 2008 Wenchuan earthquake on 10Beqtz in sediment samples from the Min Jiang river basin, in Sichuan, China. Landslide deposit material associated with the Wenchuan earthquake has consistently lower 10Beqtz than in river sediment prior to the earthquake. River sediment 10Beqtz decreased significantly following the earthquake downstream of areas of high coseismic landslide occurrence (i.e., with greater than ∼0.3% of the upstream catchment area affected by landslides), because of input of the 10Be-depleted landslide material, but showed no systematic changes where landslide occurrence was low. Changes in river sediment 10Beqtz concentration were largest in small first-order catchments but were still significant in large river basins with areas of . Spatial and temporal variability in river sediment 10Beqtz has important implications for inferring representative denudation rates in tectonically active, landslide-dominated environments, even in large basins. Although the dilution of 10Beqtz in river sediment by landslide inputs may complicate interpretation of denudation rates, it also may provide a possible opportunity to track the transport of landslide sediment. The associated uncertainties are large, but in the Wenchuan case, calculations based on 10Be mixing proportions suggest that river sediment fluxes in the 2–3 years following the earthquake increased by a similar order of magnitude in the 0.25–1 mm and the <0.25 mm size fractions, as determined from 10Beqtz mixing calculations and hydrological gauging, respectively. Such information could provide new insight into sediment transfer, with implications for secondary sediment-related hazards and for understanding the removal of mass from mountains. [Copyright &y& Elsevier]

• Assessment of reactive phases in suspended particulates in a major Arctic river. • Neodymium isotopes show equilibration between Fe-Mn oxides and dissolved loads. • Reactive iron flux from the Mackenzie River is large; 0.21(+0.06,−0.05) Tg/yr. • Sedimentary rock weathering provides an important source of labile trace metals. Riverine suspended particulate matter (SPM) is essential for the delivery of micronutrients such as iron (Fe) to the oceans. SPM is known to consist of multiple phases with differing reactivity, but their role in the delivery of elements to the oceans is poorly constrained. Here we provide new constraints on the source and composition of reactive phases in SPM from the Mackenzie River, the largest sediment source to the Arctic Ocean. Sequential leaching of SPM shows that river sediments contain labile Fe phases. We estimate the labile Fe flux is substantial (0.21(+0.06,−0.05) Tg/yr) by quantifying Fe concentrations in weak leaches of the SPM. The labile Fe phase hosts a considerable amount of rare earth elements (REE), including neodymium (Nd). We demonstrate that the labile Fe phase and dissolved load have radiogenic Nd isotope ratios that are identical within uncertainty, but up to 8 epsilon units distinct from the silicate phase. We interpret this as evidence for dynamic cycling between Fe-oxide phases in SPM and the river water, demonstrating the high reactivity of the labile Fe phase. Nd isotope and elemental molar ratios suggest that a significant amount of labile Fe- and Nd-bearing phases are derived from Fe-oxides within the sedimentary source rock rather than silicate mineral dissolution. Thus, sedimentary rock erosion and weathering provides an important source of labile Fe, manganese (Mn) and by extension potentially other trace metals. Our results imply that both past and future environmental change in the Arctic, such as permafrost thaw, may trigger changes to the supply of reactive trace metals. These results demonstrate that a re-evaluation of sediment reactivity within rivers is required where uplifted sedimentary rocks are present. [ABSTRACT FROM AUTHOR]