1. Interpreting the Drying Kinetics of a Soil Using a Macroscopic Thermodynamic Nonequilibrium of Water Between the Liquid and Vapor Phase
- Author
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B. Naon, Bruno Cousin, J. C. Benet, Fabien Cherblanc, Ali Chammari, Laboratoire de Mécanique et Génie Civil (LMGC), Université de Montpellier (UM)-Centre National de la Recherche Scientifique (CNRS), Université Polytechnique Nazi Boni Bobo-Dioulasso (UNB), Couplages en Géomécanique et Biomécanique (CGB), and Université de Montpellier (UM)-Centre National de la Recherche Scientifique (CNRS)-Université de Montpellier (UM)-Centre National de la Recherche Scientifique (CNRS)
- Subjects
drying kinetics ,Water transport ,Computer simulation ,phase change ,Chemistry ,General Chemical Engineering ,Kinetics ,Vapor phase ,0211 other engineering and technologies ,0207 environmental engineering ,Non-equilibrium thermodynamics ,Thermodynamics ,natural attenuation ,02 engineering and technology ,Mass exchange ,porous media ,non-equilibrium ,Scientific method ,[SPI.GPROC]Engineering Sciences [physics]/Chemical and Process Engineering ,Physical and Theoretical Chemistry ,020701 environmental engineering ,Porous medium ,021101 geological & geomatics engineering - Abstract
International audience; Two preliminary experiments show that a non-equilibrium situation can be easily encountered during a natural drying process. This leads us to reconsider the thermodynamic local equilibrium assumption, and propose a macroscopic two-equation model that takes into account mass exchange kinetics between the liquid and vapour phase. Numerical simulation of this theoretical model is then compared to experimental drying kinetics of soil columns. The discrepancies observed between the theoretical prediction and the experimental results are discussed. This contribution emphasizes the importance of such non-equilibrium phenomenon when modelling water transport in hygroscopic porous media.
- Published
- 2008
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