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Abstract: High-purity carbon spheres were continuously produced by pyrolysis of acetylene at 1000 °C under a nitrogen atmosphere in a vertical chemical vapor deposition reactor. The produced carbon spheres had diameters in the range of 200–500 nm and were perfectly spherical in shape with rough surfaces. High resolution transmission electron microscopy analysis revealed that the carbon spheres were constructed of heavily distorted graphene layers. The results of the X-ray diffraction pattern and Raman spectra also confirmed that the presence of disordered graphene layers was due to a low graphitization degree. In addition, thermal stability and thermal oxidation of carbon spheres were studied. The results found that the surface of the carbon spheres could be modified and the amount of oxygen-containing functional groups increased after oxidation. In summary, the method provided a catalyst-free, substrate-free, hydrogen-free, and cost-effective synthesis for continuous production of carbon spheres. [Copyright &y& Elsevier]