1. Late-model N, B, and P-co-doped carbon dots as additives for friction-reduction and anti-wear.
- Author
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Zhu, Wei, Tan, Yuhui, Tang, Weiwei, Li, Yufeng, and Tang, Yunzhi
- Subjects
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LUBRICANT additives , *BASE oils , *GREEN behavior , *LUBRICATING oils , *TRIBOLOGY , *LUBRICATION & lubricants , *ADDITIVES - Abstract
Carbon dots (CDs), a kind of burgeoning carbon-based nanomaterial, were widely used as high-efficiency lubricant additives for promoting the friction-reduction and anti-wear behaviors of green PEG-based lubricating oils. Undoubtedly, advances in CDs-based lubricant additives play a crucial role in enhancing their application prospect and utility value. Recent studies suggest that doping CDs with heteroatoms, especially multiple heteroatoms could remarkably promote their tribological performance. Therefore, the state-of-the-art N, B, and P-co-doped CDs (N,B,P-CDs) with a diameter of approximately 3.8 nm and composed of amorphous structures were synthesized by conveniently "one-step" pyrolyzing the corresponding carbon sources and dopants. Noticeably, the synthetic procedures of N,B,P-CDs were uninvolved in any pre-processing and post-processing techniques, showing favorable large-scale preparation potential. Adding suitable concentrations of N,B,P-CDs, the friction-reduction, anti-wear, and load-supporting functions of PEG200 base oil can be maximally increased by 38.1 %, 86.2 %, and 66.7 %, respectively, showing outstanding tribological performances. In addition, the tribological behaviors of N,B,P-CDs are evidently better than that of N,B-CDs and P-CDs under identical test conditions, exhibiting a multiatomic synergistic lubrication effect. According to the wear track surface analysis results and previous reports, the excellent tribological performance of N,B,P-CDs attributes to their favorable film-forming ability and nano-lubrication effect in the different friction stages. [Display omitted] • Novel N,B,P-CDs-based lubricant additives for PEG200 base oil were synthesized. • N,B,P-CDs as additives showed great anti-friction and anti-wear functions. • N,B,P-CDs possessed good multiatomic synergistic lubrication effect. • N,B,P-CDs have outstanding film-forming and nano-lubrication effects. [ABSTRACT FROM AUTHOR]
- Published
- 2023
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