1. Coordination complexes involving sydnones as ligands.
- Author
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Bantreil, Xavier, Pétry, Nicolas, and Lamaty, Frédéric
- Subjects
- *
SYDNONES , *RING formation (Chemistry) , *METALATION , *LIGANDS (Chemistry) , *SUBSTITUTION reactions - Abstract
Sydnones are mesioionic compounds studied for years for their versatile reactivity in substitution reactions, sydnone-alkyne or sydnone-alkene cycloaddition reactions. This perspective article focuses on the use of sydnones in coordination complexes, either through a metalation on one of the carbons of the sydnone ring, its modification to obtain polydentate ligands, or its use as a polar moiety that could influence the properties of the final complex. Such compounds are valuable either from a synthetic point of view or for their biological properties. [ABSTRACT FROM AUTHOR]
- Published
- 2019
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