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Your search keyword '"Bu, Xianhui"' showing total 2 results
Start Over Author "Bu, Xianhui" Topic ligands (chemistry) Journal dalton transactions: an international journal of inorganic chemistry
2 results on '"Bu, Xianhui"'

1. Charge-tunable indium–organic frameworks built from cationic, anionic, and neutral building blocks.

Author

Bu, Fei, Lin, Qipu, Zhai, Quan-Guo, Bu, Xianhui, and Feng, Pingyun

Subjects
INDIUM, LIGANDS (Chemistry), CARBOXYLIC acids, MONOMERS, CHEMICAL synthesis
Abstract

By using the same ligand, 2,5-furandicarboxylic acid (FDA), and varying synthetic conditions (especially the In3+/FDA ratio), it is possible to access three unique building blocks of indium, demonstrating charge-switching from a positive trimer to a negative monomer and leading to the synthesis of In-MOFs with tunable framework charge. [ABSTRACT FROM AUTHOR]

Published
2015
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2. A mixed ligand route for the construction of tetrahedrally coordinated porous lithium frameworksElectronic supplementary information (ESI) available: Experiment details, 1H NMR spectroscopy of synthesized ligands, powder XRD, TGA analysis and CIF files. CCDC reference numbers 794129and 794130. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c1dt10859j

Author

Zhao, Xiang, Wu, Tao, Bu, Xianhui, and Feng, Pingyun

Subjects
LIGANDS (Chemistry), COORDINATION compounds, POROUS materials, IMIDAZOLES, LITHIUM compounds, COMPLEX compounds synthesis, QUARTZ crystals, CHIRALITY, GAS absorption & adsorption
Abstract

Reported here are two 4-connected 3D frameworks based on monomeric lithium nodes, which are synthesized through a mixed ligand route. By combining a negatively charged imidazole ligand and a neutral bis(imidazolyl)methane ligand (or one of its derivatives), neutral frameworks adopting chiral quartz-dual and diamond topologies have been obtained. These materials have low framework density and can reversibly adsorb hydrogen gas. [ABSTRACT FROM AUTHOR]

Published
2011
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