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Electrocatalytic water splitting is considered to be one of the most promising technologies for large-scale sustained production of H2. Developing non-noble metal-based electrocatalytic materials with low cost, high activity and long life is the key to electrolysis of water. Transition metal sulfides (TMSs) with good electrical conductivity and a tunable electronic structure are potential candidates that are expected to replace noble metal electrocatalysts. In addition, self-supported electrodes have fast electron transfer and mass transport, resulting in enhanced kinetics and stability. In this paper, TMS self-supported electrocatalysts are taken as examples and their recent progress as hydrogen evolution reaction (HER) electrocatalysts is reviewed. The HER mechanism is first introduced. Then, based on optimizing the active sites, electrical conductivity, electronic structure and adsorption/dissociation energies of water and intermediates of the electrocatalysts, the article focuses on summarizing five modulation strategies to improve the activity and stability of TMS self-supported electrode electrocatalysts in recent years. Finally, the challenges and opportunities for the future development of TMS self-supported electrodes in the field of electrocatalytic water splitting are presented. [ABSTRACT FROM AUTHOR]

The use of a methanesulfonic acid (MSA) electrolytic system is recommended as a green method for hydrometallurgical recovery of metallic Pb from waste lead-acid batteries (LABs), contributing to the sustainable protection of the ecosystem. Nevertheless, the system's high energy consumption is a current issue due to the substantial overpotential of the oxygen evolution reaction (OER) and competitive anodic oxidation of Pb2+. Herein, we propose an IrFe/nitrogen-doped pyrolytic carbon black (IrFe/NCBp) composite as a novel OER catalyst for the MSA electrolytic system, which demonstrates advanced OER catalytic efficiency and selectivity for H2O oxidation. This can be ascribed to the catalyst's thoughtful design, which enhances the number and uniformity of Ir and Fe species via increasing the specific surface area and employing NCBp as a sustainable substrate. The optimized IrFe/NCBp composite exhibits superior OER performance, with a low 252 mV@10 mA cm−2 overpotential and a 62 mV dec−1 Tafel slope, and excellent durability in a 1 M MSA electrolyte for 30 h operation compared to commercial Ir/C. In contrast to carbon paper (CP) and commercial Ir/C anodes, the anodic reaction of IrFe/NCBp is primarily OER-driven (97%) in 1 M MSA and 0.2 M Pb2+ electrolyte for Pb recovery. This effectively circumvents the high potential oxidation of Pb2+ into PbO2, reducing the electrolytic voltage to 488 kWh for the recovery of 1 ton Pb metal. This work provides a green, low-carbon footprint solution for the MSA electrolytic system, thereby promoting the commercialization of the hydrometallurgical Pb recovery. [ABSTRACT FROM AUTHOR]