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1. Synthesis, Structural Characterization and Hirshfeld Surface Analysis of a 2D Coordination Polymer, [Co(4-dpds)(bdc)(H2O)2] 4-dpds

Author

Chih-Chieh Wang, Zi-Ling Huang, Yueh-Yi Tseng, Gia-Bin Sheu, Shih-I Lu, Gene-Hsiang Lee, and Hwo-Shuenn Sheu

Subjects
coordination polymer, metal-organic framework, Hirshfeld surface analysis, hydrogen bond, pi-pi interaction, Crystallography, QD901-999
Abstract

A two-dimensional (2D) coordination polymer, [Co(4-dpds)(bdc)(H2O)2]·4-dpds (1) (4-dpds = 4,4′-dipyridyldusulfide and bdc2− = dianion of benzenedicarboxylic acid), has been synthesized and structurally determined by single-crystal X-ray diffractometer. In 1, the bdc2− and 4-dpds both act as bridging ligands connecting the Co(II) ions to form a 2D wrinkled-like layered coordination polymer. Two wrinkled-like layered coordination polymers are mutually penetrated to generate a doubly interpenetrated framework, and then extended to its 3D architecture via the supramolecular forces between doubly interpenetrated 2D frameworks and free 4-dpds ligands by intermolecular O–H⋅⋅⋅N hydrogen bonding interaction. Crystal packing arrangements were characterized by fingerprint plots, which were derived from the Hirshfeld Surfaces analysis, and showed that intermolecular hydrogen bonding interactions are the most important interactions on the construction of the crystal 1.

Published
2020
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2. Synthesis, Structural Characterization and Hirshfeld Surface Analysis of a 2D Coordination Polymer, [Co(4-dpds)(bdc)(H2O)2] 4-dpds

Author

Gia-Bin Sheu, Yueh-Yi Tseng, Shih-I. Lu, Gene-Hsiang Lee, Chih-Chieh Wang, Hwo-Shuenn Sheu, and Zi-Ling Huang

Subjects
Materials science, Coordination polymer, General Chemical Engineering, Supramolecular chemistry, 02 engineering and technology, 010402 general chemistry, 01 natural sciences, Inorganic Chemistry, Crystal, chemistry.chemical_compound, lcsh:QD901-999, Hirshfeld surface analysis, General Materials Science, Pi interaction, pi-pi interaction, chemistry.chemical_classification, hydrogen bond, Hydrogen bond, Intermolecular force, Polymer, metal-organic framework, 021001 nanoscience & nanotechnology, Condensed Matter Physics, 0104 chemical sciences, Crystallography, coordination polymer, chemistry, Metal-organic framework, lcsh:Crystallography, 0210 nano-technology
Abstract

A two-dimensional (2D) coordination polymer, [Co(4-dpds)(bdc)(H2O)2]&middot, 4-dpds (1) (4-dpds = 4,4&prime, dipyridyldusulfide and bdc2&minus, = dianion of benzenedicarboxylic acid), has been synthesized and structurally determined by single-crystal X-ray diffractometer. In 1, the bdc2&minus, and 4-dpds both act as bridging ligands connecting the Co(II) ions to form a 2D wrinkled-like layered coordination polymer. Two wrinkled-like layered coordination polymers are mutually penetrated to generate a doubly interpenetrated framework, and then extended to its 3D architecture via the supramolecular forces between doubly interpenetrated 2D frameworks and free 4-dpds ligands by intermolecular O&ndash, H&sdot, &sdot, N hydrogen bonding interaction. Crystal packing arrangements were characterized by fingerprint plots, which were derived from the Hirshfeld Surfaces analysis, and showed that intermolecular hydrogen bonding interactions are the most important interactions on the construction of the crystal 1.

Published
2020

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