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Start Over Author "Sun, Jia Yue" Journal crystal growth & design
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3. Two-Dimensional Metal Azides Constructed by a Ln@Co6Cluster and Disordered Co3(N3)11Units

Author

Sun, Jia-Yue, Zhao, Jiong-Peng, and Liu, Fu-Chen

Abstract

Two-dimensional metal azides [LnCo9(Pzc)6(OH)3(N3)11·2(CH3OH)·2H2O]n(Ln = Gd for 1and Dy for 2) have been solvothermally prepared. In 1and 2, a heptanuclear Ln@Co6cluster is formed in which a nonacoordinate D3hLnIIIion is encapsulated in a Co6cage. The heptanuclear Ln@Co6clusters are linked by disordered Co3(N3)11units through the connection of the azide to give a 2D metal azide layer. Magnetic studies indicate ferromagnetic magnetic interactions between the ions in 1and 2.

Published
2022
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