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The development and production of new materials requires advanced analytical characterisation to explain the relation between the physico-chemical structure of the material and its properties. Highly integrated microelectronic structure analysis of surfaces with laser beams and X-ray fluorescence aided devices are found to be helpful for providing important information, including the interrelationships between physical, chemical, mechanical and durability characteristics of the new developed products. In most instances no single technique provides all the needed information and hence simultaneous application of several techniques becomes necessary. This study was aimed for hydration analysis, characterization and evaluation of a new novel non-Portland binder (NPB) with waste paper sludge ash (PSA) using FTIR and TG/DTA. The progressive formation of hydration products within the non-Portland binder was identified and their microstructural characteristics were analysed. The stable and non-expansive nature of secondary ettringite formation was also identified after a period of 365 days curing.

This review paper encompasses the inclusive approach of lime sludge valorization in construction materials. Research studies based on cement and aggregate replacement by lime sludge concludes that 10–30% lime sludge is gainfully utilized in sustainable concrete and mortar. Additional prospect for lime sludge application in construction material is the production of cement and ceramics. Significant use of lime sludge in combination with supplementary cementitious materials such as silica fume, nanosilica and fly ash is recommended for the production of cement components and ceramics. The recommendations are also suggested in accordance with the outcome of the study.

Green liquor dregs wastes coming from pulp and paper production are currently disposed in landfills at a huge cost for industry and the environment. In this work, a novel and more sustainable waste management strategy is proposed. Dregs were used for the first time as fine filler in the production of biomass fly ash-based geopolymeric mortars. The influence of the dregs incorporation amount on the fresh (geopolymer kinetics and mortars workability) and hardened-state (mechanical resistance, water absorption and capillary water absorption) properties of the mortars was evaluated. Although dregs incorporation reduce the flow workability (up to 19%), their presence and amount did not significantly alter the geopolymerization kinetics. Additionally dregs-containing mortars exhibited enhanced tensile (up to 71%) and compressive strength (up to 34%), and lower water absorption in comparison with the reference mortar. These results demonstrate the feasibility of using dregs as fine filler in geopolymers production. Moreover the mortars were produced using mainly biomass fly ash waste as aluminosilicate source which further reduces the environmental impact of the pulp and paper industry.

The paper analyses the effect of waste sludge from paper industry (paper sludge) on physical and mechanical properties of clay bricks, their microstructure and resistance to freezing and thawing. Paper sludge is not hazardous industrial waste mainly consisting of cellulose and calcite. Clay bodies were made from the mix containing from 5% to 20% of paper sludge and fired at 900 °C and 1000 °C temperatures. Open pore structure in the clay body is developed as a result of burnt cellulose fibres and calcite decarbonization. Physical and mechanical properties of clay bodies change depending on the content of added PS: shrinkage, density and compressive strength reduce, water absorption and effective porosity increase. It is recommended to add 5% of paper sludge to the clay body and fire it at 900 °C temperature, or alternatively add 5–15% of paper sludge and fire the clay body at 1000 °C temperature. In terms of resistance to freezing and thawing, such products are regarded as frost resistant in moderately aggressive environment, i.e. in structures protected from direct environmental effects.

The purpose of this study is to investigate influence of calcination and cooling conditions on pozzolanic reactivity of waste paper sludge. Calcined paper sludge (CPS) is prepared by different temperatures of calcination, duration of calcination and cooling methods. Pozzolanic activity of CPS was investigated by using API (Assessed Pozzolanic Activity Index) and SAI (Strength Activity Index) in accordance with ASTM C618 -17 (KS L 5405) and consumption of Ca(OH)2 hydrate in mortars with CPS in detail, and compared to that of commercial fly ash (FA) and blast furnace slag (BFS) used in the concrete industry. Results revealed CPS produced from waste paper sludge had excellent pozzolanic activity compared with commercial pozzolanic admixtures such as FA or BFS. Their pozzolanic activity was most excellent in calcination temperature of 700 °C, calcination duration of 2 h and cooling method of water quenching. SAI (%) of mortar with CPS produced under optimal conditions was 96% at 28 days of age, and satisfied the quality of fly ash (Class F) as specified in ASTM C618 -17 (KS L 5405). There was linear relation between API (%) and SAI (%) of mortars with CPS, and the correlation coefficient was relatively good as 0.8 at 28 days of age. The API method is recommended as rapid and appropriate evaluation of the pozzolanic activity of the CPS.

The aim of this study was to evaluate some physical and mechanical properties of the paper mill (PMS) and spruce planer shaving added cement boards. Also the effect of sludge type in consequence of waste water treatment technique on properties of wood-cement boards (WCB) was investigated. The wood/cement ratios were used as 1/3, based on the oven dry weight for the WCB manufacture. PMS was used up to 20% wt of total composite based on organic (wood) and inorganic (cement) amounts. Black sludge has shown more improvement than grey sludge on properties of WCBs, which indicates the anaerobic waste treatment technique is more effective for additive in WCB. The modulus of rupture and elasticity values of the WCBs with 5% of grey sludge, 5% and 10% of mixture of grey and black sludge were acceptable limits according to EN 634-2 standard. The mechanical strengths of all WCBs with black sludge were found above the specified EN standard. This suggests that PMS depending on sludge type may be used up to 20% wt of total composite weight for the commercial production of WCBs, which could expand the raw material base for this panel product.