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To assess the effect of long-term rice cultivation and aquic conditions on the physicochemical properties and different forms of iron and manganese and also to make a comparison with non-paddy and adjoining uncultivated soils in calcareous soils of southern Iran. The soil samples were taken from the paddy and non-paddy soils with similar parent materials and landforms. The results showed that in the paddy fields, the amounts of available (extracted by DTPA), total (extracted by nitric acid), and poorly crystalline iron and manganese oxides (extracted by ammonium oxalate) were higher than those in the non-paddy soils and show the highest amount in the surface horizons of paddy fields. In general, the paddy land use increases the iron and manganese oxides with poorly crystalline form, Feo/Fed and Mno/Mnd ratios by 1.84, 1.57, 2 and 3.2, respectively. It also reduces the amount of pedogenic iron and manganese oxides and their crystalline forms relative to the adjacent uncultivated soils. Finally, a significant positive relationship was found between the amounts of poorly crystalline iron and manganese oxides and total form and the amount of organic matter and clay in the soils under study. Also, by changing the land use from the non-paddy to paddy field, the amount of smectite increased and, in contrast, the amounts of illite and chlorite decreased. Therefore, it seems that the significant amount of organic matter introduced and their burial caused by the plowing operation and, on the other hand, their slow decomposition due to the inactivation of aerobic activities in the reduction conditions is among the factors affecting the variations of chemical properties in paddy soils and, generally, wet land soils. [ABSTRACT FROM AUTHOR]

This study has been performed to determine the impact of zinc (Zn) on cadmium (Cd) fractions in two types of calcareous soils of the Fars province in Iran at the waterlogged condition. High-reduced conditions in soil reduce Cd solubility because of the development of Cd Sulfide. Cadmium and Zn have similar physical-chemical properties; they are maintained in soil's exchangeable sites as a divalent ion. Since such few studies have been conducted in calcareous soils of Iran, we examined the effect of Zn on Cd fractions due to their similar characteristics. Treatments were three levels of Cd (0, 30 and 60 mg kg−1 of soil as CdSO4.8H2O), three levels of Zn (0, 5 and 10 mg kg−1 of soil as ZnSO4.7 H2O), three levels of incubation times (2, 4 and 8 weeks), and two types of soils (clay and sandy clay loam). The randomized completed block design (RCBD) was used for this experiment. After 2, 4, and 8 weeks of treatments, the sequential extraction technique was used to determine the Cd concentration in (WsEx), (Fe-MnOx), (Car), (OM) and (Res.) fractions. The data indicated that based on the soil texture 64% to 70% of the Cd was extracted in the WsEx and Fe-MnOx fractions. The waterlogged condition decreased the Cd concentration in the WsEx fraction and increased the Fe-MnOx, Car and OM fractions. Cd concentration in Res. fraction was higher in the clay soil while WsEx, Car and OM fractions were higher in the sandy clay loam soil. Adding Zn as zinc sulfate reduced the concentration of Cd in Fe-MnOx, Car and OM fractions but had no significant effect on the WsEx and Res. fractions. It can be concluded that the change in the Cd concentration in its chemical fractions caused by Zn addition might be from the competitive transport and adsorption interaction between these two ions. The presence of Zn reduces the concentration of Cd in those forms that are easily released into the soil solution from where they can be absorbed by plants. Abbreviation: WsEx: Water Soluble and Exchangeable; Car: Carbonate; Fe-MnOx: Iron-Manganese Oxides; OM: Organic Matter; Res: Residual [ABSTRACT FROM AUTHOR]