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Primary combustion products of boron-based propellants are incomplete combustion products that are emitted from the gas generator of a solid ducted rocket. Studying the composition of primary combustion products provides valuable information about the primary combustion process and also helps to better understand the secondary combustion process. The particle size of the primary combustion products is analyzed by a laser particle size analyzer. The qualitative analysis of the sample composition is performed by using x-ray diffraction, x-ray photoelectron spectroscopy, and thermogravimetry-differential scanning calorimetry experiments. Based on these results, an integrated quantitative analysis of the sample composition is conducted. The quantitative analysis methods include tube furnace heating, ion chromatography, infrared spectroscopy, and inductively coupled plasma chromatography. In addition, scanning electron microscopy and energy dispersive spectrometry are also used to analyze the micro-morphology and distribution of different components in the sample. The primary combustion products mainly contain B, C, BC, HBO, BO, BN, Mg, MgCl, and NHCl. BC (22-24%), HBO (20%), and B (16.8%) are the three major components, while BC, B, and C (9.8-11.8%) are the three combustible components present in the highest amounts. The oxidant NHClO is completely consumed during the primary combustion, while the metal additive Mg does not show much reactivity. The micro-morphology and distribution of BC, HBO (or BO), B, Mg, and C in the sample are investigated. Some components in the primary combustion products are found to be agglomerated, while some components are dispersed. Large particles in the sample mainly include B and Mg, while BC, HBO (or BO), and C particles are small. In general, the combustion completeness of the primary combustion products is rather low. Therefore, better understanding and controlling of the secondary combustion process is very important to improve the performance of B-based propellants. [ABSTRACT FROM AUTHOR]