1. Self-assembly of kraft lignin-acrylamide polymers.
- Author
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Hasan, Agha and Fatehi, Pedram
- Subjects
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LIGNINS , *ACRYLAMIDE , *POLYMERS , *QUARTZ crystal microbalances , *MOLECULAR weights , *PULPING , *MANUFACTURING processes - Abstract
Lignin has been produced in large quantities in the pulp manufacturing process; however, its valorization has been challenging. The production of lignin polymers has shown pathways to produce water soluble products to be used as flocculants and dispersants. However, these lignin-based polymers may interact with each other and form large flocs that could reduce their efficiency in interacting with other colloidal particles. This study aims at evaluating the self-assembly of kraft lignin-acrylamide polymers in aqueous environments under different salt concentrations. The sedimentation studies using a vertical scan analyzer showed that a higher molecular weight lignin polymer had a higher tendency for sedimentation than a lower molecular weight one. Quartz crystal microbalance with dissipation (QCM-D) was used for studying the self-assembly behavior of lignin polymers with different molecular weights. The results suggested that lignin polymer with the higher molecular weight of 96,992 g/mol had a higher tendency to self-assemble by forming a loose floc as compared to that with a lower molecular weight. Also, salt disrupted the self-assembly of lignin polymers greatly. [ABSTRACT FROM AUTHOR]
- Published
- 2019
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