1. Evidence for a High-Pressure Isostructural Transition in Nitrogen
- Author
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Chunmei Fan, Shan Liu, Jingyi Liu, Binbin Wu, Qiqi Tang, Yu Tao, Meifang Pu, Feng Zhang, Jianfu Li, Xiaoli Wang, Duanwei He, Chunyin Zhou, and Li Lei
- Subjects
General Physics and Astronomy - Abstract
We observed an isostructural phase transition in the solid nitrogen λ-N2 at approximately 50 GPa accompanied by anomalies in lattice parameters, atomic volume and Raman vibron modes. The anomalies are ascribed to a slight reorientation of the nitrogen molecules, which does not seem to affect the monoclinic symmetry (space group P21/c). Our ab initio calculations further confirm the phenomena, and suggest an optimized structure for the λ-N2 phase. In addition, a new high-pressure amorphous phase of η′-N2 was also discovered by a detailed investigation of the pressure-temperature phase diagram of nitrogen with the aim of probing the phase stability of λ-N2. Our result may provide helpful information about the crystallographic nature of dissociation transitions in diatomic molecular crystals (H2, O2, N2, etc).
- Published
- 2022