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Structural and spectroscopic properties of Sr2ZnTeO6 (SZTO) were investigated by angle-dispersive synchrotron X-ray powder diffraction and Raman spectroscopy in a diamond anvil cell up to 31 GPa at room temperature. Although SZTO remained stable up to the highest pressure, the different pressure coefficients of the normalized axial compressibility were obtained as βab=8.16x10-3 GPa-1 and βc=7.61x10-3 GPa-1. The bulk modulus B0 was determined to be 190(1) GPa by fitting the pressure--volume data using the Birch--Murnaghan equation of state. All the observed Raman modes exhibited a broadening effect under high pressure. The vibrational band ν1 around 765 cm-1, which is associated with the Te-O stretching mode in the basal plane of the TeO6 octahedron had the largest pressure coefficient, and the Grüneisen parameters for all the observed phonon modes were also calculated and presented. These parameters could be used to measure the amount of uniaxial or biaxial strain, providing a fundamental tool for monitoring the magnitude of the shift of phonon frequencies with strains. [ABSTRACT FROM AUTHOR]

A new structural phase of MgV2O6 was obtained by a high-pressure, high-temperature (HPHT) synthesis method. The new phase was investigated by the Rietveld analysis of X-ray powder diffraction data, showing space group Pbcn (No. 60) symmetry and a = 13.6113(6) Å (1 Å = 0.1 nm), b = 5.5809(1) Å, c = 4.8566(3) Å, V = 368.93(2) Å3 (Z = 4). High pressure behavior was studied by Raman spectroscopy at room temperature. Under 22.5 GPa, there was no sign of a structural phase transition in the spectra, demonstrating stability of the HPHT phase up to the highest pressure. [ABSTRACT FROM AUTHOR]

Structural and spectroscopic properties of Sr2ZnTeO6 (SZTO) were investigated by angle-dispersive synchrotron X-ray powder diffraction and Raman spectroscopy in a diamond anvil cell up to 31 GPa at room temperature. Although SZTO remained stable up to the highest pressure, the different pressure coefficients of the normalized axial compressibility were obtained as βab=8.16x10-3 GPa-1 and βc=7.61x10-3 GPa-1. The bulk modulus B0 was determined to be 190(1) GPa by fitting the pressure--volume data using the Birch--Murnaghan equation of state. All the observed Raman modes exhibited a broadening effect under high pressure. The vibrational band ν1 around 765 cm-1, which is associated with the Te-O stretching mode in the basal plane of the TeO6 octahedron had the largest pressure coefficient, and the Grüneisen parameters for all the observed phonon modes were also calculated and presented. These parameters could be used to measure the amount of uniaxial or biaxial strain, providing a fundamental tool for monitoring the magnitude of the shift of phonon frequencies with strains. [ABSTRACT FROM AUTHOR]