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Coupling microalgae cultivation with wastewater treatment is a promising environmentally sustainable development strategy. However, toxics such as Bisphenol A (BPA) in wastewater damage microalgae cells and reduces bioresources production. Phytohormone regulation has the potential to solve this issue. However, phytohormone research is still in its infancy. In this work, 0.2 μM naphthyl acetic acid (NAA) significantly enhanced Chlorella vulgaris BPA detoxification by 127.3% and Chlorella biomass production by 46.4%. NAA helps Chlorella convert bisphenol A into small non-toxic intermediates by enhancing the expression of associated enzymes. Simultaneously, NAA promoted carbon fixation and photosynthetic metabolism. Activation of the mitogen-activated protein kinase (MAPK) pathway strengthened the downstream antioxidant system while improving photosynthesis and intracellular starch and lipid synthesis. Carbohydrates, pigment, and lipid production was significantly enhanced by 20.0%, 46.9%, and 21.8%, respectively. A new insight is provided into how phytohormones may increase microalgae in wastewater's bioresource transformation and toxicity resistance.

Recently, ultraviolet light-emitting diodes (UV-LEDs) and chlorine combined system has been employed as an emerging advanced oxidation process. However, UV-LEDs were commonly considered as monochromatic UV sources. In this study, the obvious quantum yields of chlorine photolysis under 265 nm and 280 nm LEDs irradiations were investigated with treating LEDs as polychromatic UV sources. Particularly, Φobs-poly of HOCl and OCl⁻ for 265 nm LED were found to be 1.50 and 0.70 mol E−1, respectively, whereas Φobs-poly of HOCl and OCl⁻ for 280 nm LED were 1.28 and 0.64 mol E−1, respectively. It was identified that Φobs-poly were 5.66–14.63 % lower than Φobs-mono. This suggests that obvious quantum yield using peak emission wavelength would overestimate the true quantum yield. The production of radical species in LED UV/chlorine systems were determined by the degradation of BA, and illustrated by a mathematical model. Different trends were observed for 265 nm and 280 nm LED UV/chlorine systems as pH increased from 5.0 to 10.0. As pH increased, the formation of OH continuously decreased in both 265 nm and 280 nm LED systems. The formation of Cl increased at neutral pH and more Cl and OH were formed due to the higher molar absorbance coefficient at 280 nm. The chlorine dose-dependent effects on radical productions at pH of 5.0, 7.5 and 10.0 were also assessed. At pH of 5.0, OH was the main radical product and had linear correlation with chlorine dose. At pH of 7.5, the productions of OH and Cl showed similar profiles that increased rapidly at low chlorine dosage and then slowed down.

The prepared g-C

Rice as a paddy field crops, iron-containing materials application could induce its iron plaque formation, thereby affecting cadmium (Cd) transportation in the rhizosphere and its uptake in root. In this study, a hydroponic experiment was conducted to investigate the effects of three exogenous iron materials, namely nano-Fe

The prepared g-C3N4 under morphology controlling shows better physic and chemical performance. The synergistic effect of POM and g-C3N4 in the hybrid improves its high photocatalytic capability. The research indicates that g–C3N4–based material is a potential photoelectrode for PEC degradation. Besides, the PMoV nanocomposite shows better activities in the PEC and removal efficiency of RhB. Compared with the same PEC system, the degradation time of RhB is shorter and the degradation efficiency is higher for the MCN/PMoV catalysts.

Rice as a paddy field crops, iron-containing materials application could induce its iron plaque formation, thereby affecting cadmium (Cd) transportation in the rhizosphere and its uptake in root. In this study, a hydroponic experiment was conducted to investigate the effects of three exogenous iron materials, namely nano-Fe3O4-modified biochar (BC–Fe), chelated iron (EDTA-Fe), and ferrous sulfate (FeSO4), on the iron plaque formation on the surface of rice root, and to investigate the effects of formed iron plaque on the absorption, migration, and transportation of Cd and Fe in rice plant. The results showed that yellow-brown and brown iron plaque was formed on surface cells of the Fe-treated rice root, and some black particles were embedded in the iron plaque formed by BC-Fe. The proportion of crystallized iron plaque (31.8%–35.9%) formed by BC-Fe was much higher than that formed by EDTA-Fe and FeSO4. The Cd concentrations in the crystallized iron plaque formed by BC-Fe were 7.64–13.0 mg·kg−1, and increased with the increasing of Fe concentrations in the plaque. The Cd translocation factor from root to stem (TFr-s) and the Cd translocation factor from stem to leaf (TFs-l) with BC-Fe treatment decreased by 84.7% and 80.0%, respectively. The results demonstrated that application BC-Fe promoted the formation of iron plaque and enhanced the sequestration of Cd and Fe in roots, thus reduced the transportation and accumulation of Cd in aerial rice tissues.

Wastewater reclamation in the textile industry has attracted considerable attention. In this study, catalytic ozonation by regenerated granular activated carbon (rGAC) and its combination with biological activated carbon (BAC) was investigated for the reclamation of a real bio-treated dyeing and finishing wastewater (BDFW). Catalytic ozonation by rGAC (O3/rGAC) was 1.6–2.0 times more efficient than ozonation alone for pollutants degradation. Although iron oxide loaded rGAC (rGAC-Fe) improved the performance of catalytic ozonation by 14%–25%, but was labile ( 20 days). Catalytic ozonation improved the generation of •OH, contributing 1.1–1.7 times faster of chromophores decomposition and 0.24–0.55 times more increase of biodegradability than ozonation. However, catalytic ozonation increased the acute toxicity of BDFW by two times. The combination of O3/rGAC and BAC can synergistically reduce COD, chromophores, and color in BDFW during 45-day's continuous operation, the improvements than O3/rGAC being 21.0%, 18.8%, and 13.6%, respectively. Moreover, although O3/rGAC of BDFW increased the toxicity from 98.3 to 146.5 μg-HgCl2/L, post BAC significantly reduced the toxicity to 13.1 μg-HgCl2/L. Engineering practice of water reclamation by O3/rGAC-BAC was approved to be feasible based on both the water quality of treated water and the operation cost.

The growing population in urban area impacted the water quality of the urban rivers receiving treated municipal wastewater. Polycyclic aromatic hydrocarbons (PAHs) and their derivatives (SPAHs) are corresponding to the population density. In this study, the concentrations of 16 PAHs and 17 SPAHs, including 4 methyl PAHs (MPAHs), 4 oxygenated PAHs and 9 chlorinated PAHs were investigated in the major urban rivers receiving the effluent from 5 major wastewater treatment plants (WWTPs) in the mega city Beijing. The concentrations of ΣSPAHs (307 ± 68 ng/L) were similar to ΣPAHs (321 ± 92 ng/L) in the total phase (aqueous + particulate) suggesting that SPAHs in the urban rivers should be taken into consideration. The lower concentrations of ΣPAHs and ΣMPAHs in this study than the wastewater receiving rivers and WWTPs effluent previously (2010–2013), as well as the lower concentration in the heating seasons than the non-heating season in the investigated year implied the reduction of coal combustion for heating and power generation in recent years. Although WWTPs effluent was theoretically the only source to the urban rivers in the investigated season, April and November, PAHs and SPAHs in most rivers were demonstrated to be originated from other unknown sources besides the WWTPs effluent. The reduction from the original source, coal combustion (33% and 30%), was more efficient than from the wastewater treatment upgrading (15%) for the reduction of PAHs and SPAHs in the urban rivers.