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Modernized lifestyle and increased industrialization threaten living organisms because of the pollutants released from industries and household wastes. The presence of even small amounts of pollutants (organic pollutants (OPs) and inorganic pollutants-heavy metals (HMs)) shows significant effects. Thus wastewater treatment is urgently needed before being subjected to use. Many methods and materials have been developed and reported for the removal of pollutants from wastewater. This review focused on the removal of both OPs and HMs using bismuth-based (Bi-based) materials because of their low toxicity and excellent properties compared to other metals. Bi-based materials as a photocatalyst for photodegradation of OPs are discussed in detail with synthesis methods. Further, since few reviews are available on the Bi-based material for the removal and sensing of HMs, this topic was intentionally summarized. About 200 published articles and reviews have been reviewed here. Additionally, the key point that needs to be focused on the development of Bi-based photocatalysts for the removal of OPs and for upgrading the Bi-based materials as adsorbents for HMs are conferred in the outlook. This will help many researchers in their upcoming work.

Hydrogen is one of the cleanest renewable and environmentally friendly energy resource that can be generated through water splitting. However, hydrogen evolution occurs at high overpotential, and efficient hydrogen evolution catalysts are desired to replace state-of-the-art catalysts such as platinum. In the present work, a novel molybdenum disulfide decorated banana peel porous carbon (MoS

A simple, low-cost, and green route for the preparation of lotus carbon (LC) materials using lotus parts including leaves, flowers, fruits (seed pods), and stems as a renewable precursor is reported. Different porous carbons, leaf-carbon (LF-carbon), flower-carbon (FL-carbon), fruit-carbon (FR-carbon), and stem-carbon (ST-carbon) were synthesized from different parts of the lotus plant by simple carbonization method. The as-synthesized LC materials were well-characterized by many techniques such as electron microscopy and spectroscopy techniques, X-ray diffraction, and BET-surface area analysis. These techniques confirmed the porous structure of LC materials and the existence of heteroatoms in the prepared LC materials. The mesoporous structure of LC materials suggested employing it for the supercapacitor applications. The obtained FR-Carbon exhibits a high specific capacitance of 160 F/g in a three-electrode system in an aqueous 1 M H

In this study, a novel and sustainable approach was used to synthesize nitrogen-doped carbon dots (NCDs) from the waste biomass of Poa Pratensis (Kentucky bluegrass (KB)) by a facile hydrothermal method. The prepared KBNCDs were subjected to various characterization techniques, including X-ray diffraction, X-ray photoelectron spectroscopy, transmission electron microscopy, and Fourier-transform infrared spectroscopy to verify the formation of carbon dots and their surface functional groups. The KBNCDs exhibited good hydrophilic fluorescence (FLU) properties with an acceptable quantum yield (7%). The synthesized KBNCDs showed excitation wavelength-dependent FLU emission behavior with strong cyan-blue FLU upon irradiation with 365 nm UV-light. The hydrophilic optical properties of the as-synthesized KBNCDs were used to detect Fe

Heavy metal ions (HMI) have attracted worldwide concern due to their serious environmental pollution which led to the risk of health conditions. From Red Malus floribunda fruits, nitrogen-doped carbon dots (N-CDs) were prepared, followed by hybrid-spherical shaped hydrogel particles (CGCDs) were prepared. The prepared CGCDs were utilized as adsorbents for HMI-(Hg(II), Cd(II), Pb(II), and Cr(III)) from water. N-CDs with about 4.0 nm in diameter were characterized by various techniques such as field emission-scanning electron microscopy (FE-SEM) and attenuated total reflection-fourier transform infrared spectroscopy (ATR-FTIR) that confirm the presence of nitrogen, oxygen, and carbon functionalities. The prepared spherical CGCDs were characterized very well before it was used as HMI adsorbents. The sizes of the CGCDs were ranges between 20 and 300 μm and the degree of swelling was calculated as 1320 %. ATR-FTIR and X-ray diffraction analyses reveal the presence of N-CDs in CGCDs. Further, FE-SEM confirms the spherical shape morphology of CGCDs. Three different concentrations of HMI solutions were 500 mg/L, 1000 mg/L, and 1500 mg/L. Hg(II) adsorbed proficiently by CGCDs in single metal ion systems with ~72 % and almost complete removal of Hg(II) ions (99 %) in multiple metal ion systems was observed. Moreover, all metal ions Hg(II), Cd(II), Pb(II), and Cr(III) were efficiently (>70 %) removed in multiple systems by CGCDs. After HMI adsorption experiments, the elemental mapping from FE-SEM and X-ray photoelectron spectroscopy studies conveys the presence of HMI on CGCDs. This suggests that CGCDs would be a suitable adsorbent for the simultaneous removal of multiple HMI from wastewater.