1. Mixed biosorbent of agro waste and bacterial biomass for the separation of Pb(II) ions from water system
- Author
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S. Karishma, P.R. Yaashikaa, S. Swetha, Anbalagan Saravanan, P. Senthil Kumar, and S. Jeevanantham
- Subjects
Environmental Engineering ,Health, Toxicology and Mutagenesis ,0208 environmental biotechnology ,Kinetics ,Biomass ,02 engineering and technology ,010501 environmental sciences ,01 natural sciences ,symbols.namesake ,Adsorption ,Environmental Chemistry ,Fourier transform infrared spectroscopy ,Rhodobacteraceae ,0105 earth and related environmental sciences ,Ions ,Aqueous solution ,Chemistry ,Public Health, Environmental and Occupational Health ,Chemical modification ,Langmuir adsorption model ,Water ,Sorption ,General Medicine ,General Chemistry ,Hydrogen-Ion Concentration ,Pollution ,020801 environmental engineering ,Lead ,symbols ,Thermodynamics ,Water Pollutants, Chemical ,Nuclear chemistry - Abstract
Adsorption of Pb(II) ions in aqueous systems by newly developed mixed biomass has been explored. Mixed biomass was prepared from agro-waste (raw Banyan tree bark, RBTB) and bacterial biomass (Pannonibacter phragmitetus). Chemical modification by sulphuric acid treatment of raw banyan tree bark (SMBTB) was accomplished for the effective separation of toxic Pb(II) ions from the aquatic system. FTIR, SEM and EDX analysis was utilized to deduce sorption characteristics of mixed biomass. Pb(II) ions maximal removal has occurred at pH-6.0, lead (II) ions concentration-25 mg/L, time and mixed biomass dosage (60 min and 3.5 g/L for RBTB – Pannonibacter phragmitetus; 30 min and 1.5 g/L for SMBTB – Pannonibacter phragmitetus) and temperature (30 °C). Data from equilibrium isotherm and kinetic analysis was best suited to the Langmuir model and pseudo-first-order kinetics. The spontaneous and exothermic nature of Pb(II) ions removal was described by thermodynamic parameters. The mixed biomass proved to be an effective and potential mixed biosorbent for toxic lead removal from solutions.
- Published
- 2020