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Trace metals pollution, distribution and associated health risk were evaluated in the arid coastal aquifer, Hada Al-Sham, Western Saudi Arabia using an integrated approach namely heavy metal pollution index (HPI), contamination index (C d ), health risk assessment (HRA) model and multivariate statistical analysis. Groundwater samples (n = 47) were analysed for EC, pH, TDS, Ag, Al, B, Ba, Co, Cd, Cr, Cu, Fe, Mo, Ni, Pb, V and Zn. Groundwater is mostly alkaline (72%) with high salinity (TDS >1500 mg/l, 77%). Average trace metals concentrations are in the dominance order of B > Cu > Al > Mo > Pb > V > Ba > Zn > Ni > Cr > Fe > Ag. Groundwater (100% wells) is unsafe for drinking based on V, Mo, Al concentrations followed by the Pb (96%), B (91%), Ni (72%), Cr (23%), Cu (17%) and Ag (6%), which exceeded the WHO and USEPA prescribed limits. Results of HPI and C d also implied the high contamination and enhanced level of metals in the groundwater. Chronic daily intake (CDI oral ), hazard quotient (HQ) and total hazard quotient (THQ) were employed for health risk assessment. HQ values reveal that 100% (Al, Mo), 85% (Cu), 21% (B), 13% (Cr) and 6% (Pb) of samples exceeded the recommended limit (>1), which can cause an adverse health risk to adult and children. Pearson correlation, principal components analyses, and Hierarchical cluster analysis justified that aluminium silicates weathering and Fe oxides/hydroxides dissolution (Pb, Cr, Ni, Fe, Ag, Al, Mo and V), evaporation, anthropogenic input (Cu and B) and dissolution of carbonate and sulphate minerals (Ba and Zn) controlled the water chemistry in this aquifer. This study recommends a proper treatment of the groundwater to be safe for various uses. The comprehensive approach, employed here, is applicable to any arid aquifers worldwide., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

The first systematic study on high fluoride contaminated fractured rock aquifer in South Africa using geochemical and chemometric approach is presented. Groundwater samples were collected from 49 boreholes and analysed for EC, pH, major and minor ions. The groundwater with high fluoride is associated with NaCl water types. The groundwater chemistry is governed by mineral weathering, evaporation and wastewater infiltration. PHREEQC modelling indicates that carbonate mineral saturation is decreasing with increasing salinity due to evaporation whereas fluorite saturation increases with increasing F being one of the prime controlling factors. Silicate minerals namely chalcedony, quartz and talc express saturation and over-saturation while chrysotile and sepiolite are undersaturated in most of the samples. PCA provided four factors and justified the role of mineral weathering, evaporation, ion exchange, longer residence time and anthropogenic impacts on water chemistry. R-mode and Q-mode cluster analysis resulted in four clusters. In cluster 1, (29%) of groundwater is less mineralized due to recent recharge. In cluster 2 (45%), groundwater chemistry is governed by weathering of silicates and fluorite minerals. Cluster 3 (20%) reveals the impact of anthropogenic activities and induced mineral weathering. Cluster 4 shows high EC, TDS, major ions, F and low HCO 3 implying that groundwater is affected by evaporation and longer residence time promoting mineral-water interaction and precipitation of carbonate minerals. More than 50% of the study area is degraded due to fluoride contamination which requires proper remedial actions and further investigations on human health risk due to impact of fluoride contamination in groundwater is recommended., (Copyright © 2019 Elsevier Ltd. All rights reserved.)