1. Simultaneous denitrification, phosphorus recovery and low sulfate production in a recirculated pyrite-packed biofilter (RPPB).
- Author
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Di Capua F, Mascolo MC, Pirozzi F, and Esposito G
- Subjects
- Chemical Precipitation, Filtration instrumentation, Nitrogen isolation & purification, Sulfur chemistry, Sulfur isolation & purification, Bioreactors, Denitrification, Filtration methods, Iron isolation & purification, Phosphorus isolation & purification, Sulfides
- Abstract
The simultaneous removal of nitrate (15 mg N-NO
3 - L-1 ) and phosphate (12 mg P-PO4 3- L-1 ) from nutrient-polluted synthetic water was investigated in a recirculated pyrite-packed biofilter (RPPB) under hydraulic retention time (HRT) ranging from 2 to 11 h. HRT values ≥ 8 h resulted in nitrate and phosphate average removal efficiency (RE) higher than 90% and 70%, respectively. Decrease of HRT to 2 h significantly reduced the RE of both nitrogen and phosphorus. The RPPB showed high resiliency as reactor performance recovered immediately after HRT increase to 5 h. Solid-phase characterization of pyrite granules and backwashing material collected from the RPPB at the end of the study revealed that iron-phosphate, -hydroxide and -sulfate precipitated in the bioreactor. Thermodynamic modeling predicted the formation of S0 during the study. Residence time distribution tests showed semi-complete mixing hydrodynamic flow conditions in the RPPB. The RPPB can be considered an elegant and low-cost technology coupling biological nitrogen removal to the recovery of phosphorus, iron and sulfur via chemical precipitation., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2020 Elsevier Ltd. All rights reserved.)- Published
- 2020
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