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Composting is very robust and efficient for the biodegradation of organic waste; however secondary pollutants, namely greenhouse gases (GHGs) and odorous emissions, are environmental concerns during this process. Biochar addition to compost has attracted the interest of scientists with a lot of publication in recent years because it has addressed this matter and enhanced the quality of compost mixture. This review aims to evaluate the role of biochar during organic waste composting and identify the gaps of knowledge in this field. Moreover, the research direction to fill knowledge gaps was proposed and highlighted. Results demonstrated the commonly referenced conditions during composting mixed biochar should be reached such as pH (6.5-7.5), moisture (50-60%), initial C/N ratio (20-25:1), biochar doses (1-20% w/w), improved oxygen content availability, enhanced the performance and humification, accelerating organic matter decomposition through faster microbial growth. Biochar significantly decreased GHGs and odorous emissions by adding a 5-10% dosage range due to its larger surface area and porosity. On the other hand, with high exchange capacity and interaction with organic matters, biochar enhanced the composting performance humification (e.g., formation humic and fulvic acid). Biochar could extend the thermophilic phase of composting, reduce the pH value, NH

Microplastic pollution is becoming a global challenge due to its long-term accumulation in the environment, causing adverse effects on human health and the ecosystem. Sludge discharged from wastewater treatment plants (WWTPs) plays a critical role as a carrier and primary source of environmental microplastic contamination. A significantly average microplastic variation between 1000 and 301,400 particles kg

Composting is a promising technology to decompose organic waste into humus-like high-quality compost, which can be used as organic fertilizer. However, greenhouse gases (N

The overall dioctyl terephthalate (DOTP) degradation efficiency during food waste composting was 98%. The thermophilic phases contributed to 76% of the overall degradation efficiency, followed by the maturation phase (22%), then the mesophilic phase (0.7%). The thermophilic phase had the highest specific degradation rate of 0.149 d-1. The progression of the bacterial community during the composting process was investigated to understand DOTP biodegradation. The results showed that the bacterial richness and the alpha diversity of the DOTP composting were similar to a typical composting process, indicating that the high concentration of DOTP did not hinder the thriving and evolution of the bacterial community. Additionally, Firmicutes was the most dominant at the phylum level, followed by Proteobacteria and Bacteroidetes. Bacilli was the most dominant class (70%) in the mesophilic phase, with the abundance decreasing thereafter in the thermophilic and maturation phase. Moreover, Lactobacillus sp. was the dominant species at the beginning of the experiment, which was probably responsible for DOTP biodegradation. The high removal efficiency observed in the maturation phase indicates that degradation occurs in all the composting phases, and that compost can be used to enhance natural attenuation. These findings provide a better understanding of the bacterial communities during biodegradation of DOTP and plasticizers via food waste composting and should facilitate the development of appropriate green bioremediation technologies.

A reaction mixture containing DDT (1,1,1-trichloro-2,2-bis(p-chlorophenyl)ethane), methylene green (as the photosensitizer), and triethylamine (as the electron donor) in acetonitrile:water (1:1) was irradiated by an ordinary 150-W GE-Miser spotlight to facilitate visible-light photosensitized DDT dehalogenation. The intermediates and reaction products were identified by GC/MS (gas chromatography/mass spectrometer) and NMR (nuclear magnetic resonance). The photosensitized dehalogenation method partially degraded DDT via an electron transfer relay mechanism. Results indicate that DDT lost about three chlorines after a total of 19 days of irradiation. Aliphatic chlorines were found to be removed easier than aromatic chlorines. Various types of reductants were compared for electron donation efficiency, and photosensitizer concentration was optimized for our reaction system. In most cases, clean and simple dechlorinated products were observed. The proposed photosensitized reduction was coexisted with a thermal elimination effect for the first chlorine removal of DDT, and the photosensitized electron transfer reduction was shown to be the dominating mechanism responsible for further dechlorination after the initial stage. A sequential dechlorination pathway was proposed, with each successive dehalogenation, the reaction proceeds more slowly. The results have shown the feasibility of utilizing visible light, nontoxic dyes and electron donors to render a toxic compound less toxic and to enhance the natural carbon regeneration rates.

TiO2/UV photocatalytic oxidation of DDT (1,1,1-trichloro-2,2-bis(p-chlorophenyl)ethane), 1,2,3-trichlorobenzene and 4-chlorophenol were examined in aqueous solution in the presence of humic substances and organic mixtures to study if the degradation rates were affected. Both commercial and natural humic substances were observed to retard the photodegradation rates, with a greater effect from the natural humic substances. Acetonitrile and isopropanol also caused significant retardation of 4-chlorophenol photodegradation. The overall retardation can be attributed to the combination of light attenuation, inhibition and competition effects. Moreover, the TiO2/UV system favors the decomposition of compounds that have stronger adsorption onto the TiO2 surface. To engineer effective treatment facilities that use the TiO2/UV system for the treatment of toxic substances in wastewater, the methodology must allow for concerns about adventitious species which are present.

The photocatalytic bleaching of dyes using TiO2 has appeared promising in laboratory studies, but little attention has been focused on whether other species such as might be found in wastewater have a deleterious effect on the photobleaching. This study describes the effects that result from the presence of ionic species, organic solvents and humic substances on the photobleaching of several dyes. The manner in which the photobleaching was affected by the presence of adventitious materials was carefully examined with an eye toward elucidating the mechanistic origin of the loss of the photochemical efficiency in the reaction. The overall retardation effects can be attributed to the combination of light attenuation, inhibition and competition effects.

Titanium dioxide was shown to be generally effective as a catalyst for photobleaching many structural classes of organic dyes in aqueous solution, using visible light. However, results from study of 15 dyes indicate that photobleaching rates differ significantly from families of dyes with different functionalities, and are dependent on the light source and crystalline form of TiO2 used. Sorption characteristic on the TiO2 surface and the aqueous solubility of the dyes also play an important role in the photobleaching rate. Kinetic analysis indicates that the dye photobleaching rates can usually be approximated as pseudo-first-order kinetics. In addition to the generally proposed photocatalytic oxidation mechanism for TiO2 reactions, we observed evidence for two kinds of electron transfer mechanisms that are “photosensitized reduction” and “photosensitized oxidation”. Natural sunlight was effectively used to photobleach some of the dyes.