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The degradation process of bisphenol S (BPS) in ozone/peroxymonosulfate (O 3 /PMS) system was systematically explored. The results showed that the removal efficiency of BPS by O 3 could be significantly improved with addition of PMS. Compared with ozonation alone, the pseudo-first-order constant (k obs ) was increased by 2-5 times after adding 400 μM PMS. In O 3 /PMS system, accelerated removal of BPS was observed under neutral and alkaline conditions. The removal efficiency of BPS reached 100% after 40 s of reaction at pH 7.0, with the k obs of 0.098 s -1 . Moreover, Cu 2+ had a catalytic effect on the O 3 /PMS system, because it could catalyze the decomposition of ozone and PMS to produce •OH and SO 4 •- , respectively. Electron paramagnetic resonance illustrated that •OH and SO 4 •- were the reactive species in O 3 /PMS system. Twelve intermediates were identified by mass spectrometry, and the degradation reactions in O 3 /PMS system mainly included hydroxylation, sulfate addition, polymerization and β-scission. Finally, the toxicity of the products was evaluated by the EOCSAR program. Our results introduce an efficient method for BPS removal and would provide some guidance for the development of O 3 -based advanced oxidation technology., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Marine hazardous contaminants, such as cadmium (Cd) and lead (Pb), pose significant risks to both human health and aquatic organisms. Traditional methods may not remove contaminants to safe levels, leading to the release of hazardous materials into marine environments. This research proposes polymeric membrane bioreactors as a potential solution to this problem. We determined Cd and Pb levels in three freshwater fish species (Rita, Ompok bimaculatus, and Heteropneustes fossils) from two distinctive regions (Zone 1 and Zone 2). Additionally, Cd and Pb concentrations in feeding materials, water, and sediments were analyzed to estimate daily intake and potential hazardous effects of these contaminants on the fish species. These findings underscore the need for effective regulatory measures and policies to reduce the discharge of hazardous contaminants into freshwater and marine environments, protecting both human health and the environment. Implementing polymeric membrane bioreactors in wastewater treatment and industrial facilities could mitigate the risks associated with consuming contaminated fish species. Significantly, the Cd and Pb levels in all three fish species from both fishponds exceeded the Food and Agriculture Organization's (FAO) maximum permissible limits. These findings carry important implications for policymakers, regulators, and industries, urging them to act appropriately to ensure the safety of the environment and public health. This study suggests that polymeric membrane bioreactors are a promising technological approach to address marine contamination, emphasizing their potential role in safeguarding human health and aquatic ecosystems., Competing Interests: Declaration of competing interest The authors declare no conflict of interests., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

In this study, the oxidation of 1-naphthol (1-NAP) and 2-naphthol (2-NAP) by Fe(VI) was investigated. The impacts of operating factors were investigated through a series of kinetic experiments, including Fe(VI) dosages, pH and coexisting ions (Ca 2+ , Mg 2+ , Cu2 + , Fe 3+ , Cl - , SO 4 2- , NO 3 - and CO 3 2- ). Almost 100% elimination of both 1-NAP and 2-NAP could be achieved within 300 s at pH 9.0 and 25 °C. Cu 2+ could significantly improve the degradation efficiency of 1-NAP and 2-NAP, but the impacts of other ions were negligible. The liquid chromatography-mass spectrometry was used to identify the transformation products of 1-NAP and 2-NAP in Fe(VI) system, and the degradation pathways were proposed accordingly. Electron transfer mediated polymerization reaction was the dominant transformation pathway in the elimination of NAP by Fe(VI) oxidation. After 300 s of oxidation, heptamers and hexamers were found as the final coupling products during the removal of 1-NAP and 2-NAP, respectively. Theoretical calculations demonstrated that the hydrogen abstraction and electron transfer reaction would easily occur at the hydroxyl groups of 1-NAP and 2-NAP, producing NAP phenoxy radicals for subsequent coupling reaction. Moreover, since the electron transfer reactions between Fe(VI) and NAP molecules were barrierless and could occur spontaneously, the theoretical calculation results also confirmed the priority of coupling reaction in Fe(VI) system. This work indicated that the Fe(VI) oxidation was an effective way for removing naphthol, which may help us understand the reaction mechanism between phenolic compounds with Fe(VI)., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

The removal of Bisphonel AF (BPAF) by zero-valent iron activated persulfate (Fe 0 /PS) system was systematically evaluated in this work. 30.0 μM BPAF was removed by 94.4% in 60 min of treatment under optimal conditions of pH = 3.0 and [PS] = [Fe 0 ] = 3.0 mM. Cl - significantly accelerated the removal of BPAF, resulting from accelerated Fe 2+ release and reactive chlorine species (RCS) formation. Liquid chromatography-time-of-flight-mass spectrometry identified thirteen degradation products, and bond breaking, coupling reactions, hydroxylation and sulfate addition were considered as the major transformation pathways. When Cl - was present, six new chlorinated byproducts were also generated. Based on density functional theory (DFT) calculations, the occurrence of radical addition reactions was verified and the preferential reaction channels were determined. Significantly BPAF degradation products were less toxic, according to toxicity assessment by the ECOSAR program. Moreover, a high removal efficiency of BPAF (>90%) was also obtained in the three actual water matrixes. The present work demonstrates the feasibility of Fe 0 /PS system for treating BPAF, which could also provide new insights into the influence of coexisting Cl - on the environmental fate of organic pollutants in sulfate radicals based advanced oxidation processes., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

In the late 1990s, severe pollution by persistent organic contaminants (POCs) was observed in Lake Sihwa by use of a combination of instrumental analyses and in vitro bioassays. To determine long-term changes (>15-year gaps) in distributions of POCs and their potential toxic potencies in the given region, sediment assessments were reconducted. Target chemicals include polycyclic aromatic hydrocarbons (PAHs), alkylphenols (APs), and recently reported emerging chemicals, styrene oligomers (SOs). We employed in vitro bioassays (such as H4IIE-luc and MVLN) to determine potential sediment toxicities. The reduction rates of mean concentrations of APs and SOs in sediments between the two sampling years (1998 vs. 2015) were estimated to be 99% and 67%, respectively. Although APs and SOs significantly declined over the 15-year period, concentrations of PAHs were consistent. Results of the bioassays were consistent with the instrumental data, with relatively great concentrations of all target compounds being detected, particularly in inland creeks. Compositions of all target compounds exhibited changes in homologue patterns over the 15 years considered. This result indicated varying and/or continuing sources in this region. In particular, PAHs were dominated by higher-molecular-weight PAHs (e.g., benzo[g,h,i]perylene and benzo[b]fluoranthene) in recent years. This result might indicate consumption of oil-related fuels. Quantitative potency balance analysis revealed that concentrations of instrumentally-derived equivalents accounted for as little as 18.5% of bioassay-derived equivalents, which indicated significant amounts of unknown and/or unmeasured compounds were present. The present study documented the continuing severe pollution by selected POCs in the Lake Sihwa region over the last 15 years, indicating a lack of management in the area studied., (Copyright © 2017 Elsevier Ltd. All rights reserved.)