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Abstract: The importance of good indoor air quality for the health of the individual was recognized as long as 150years ago and that period also saw recommendations, which essentially related to questions of ventilation and carbon dioxide. The first evaluation standards for organic and inorganic substances were laid down in the 1970s, often on an empirical basis. It was in the mid-1980s of the 20th century that a shift occurred towards systematically evaluating the results of indoor air measurements, carrying out representative environmental surveys and deriving guideline values and reference values on the basis of toxicological, epidemiological and statistical criteria. Generally speaking the indoor environment is an area which can only be assessed with difficulty since its occupants are in most cases exposed to mixtures of substances and there can be great local and temporal variations in the substance spectrum. Data are available today for a large number of substances and this makes it possible, with the aid of statistically derived reference values and toxicologically based guideline values, to make useful recommendations regarding good indoor air quality. Nevertheless, it is still difficult to evaluate reactive compounds and reaction products. What is disadvantageous, however, is the fact that different guideline values may be published for one and the same substance, whose justification and area of application are often not transparent. A guideline or reference value can only be regarded as rational when necessary and when a strategy for its verification is available. [Copyright &y& Elsevier]

Materials Institute Lavoisier (MIL) metal organic frameworks (MOFs) are known for their potential to adsorb gaseous organic pollutants. This study explores the synergistic effects between the selection of central metals (e.g., titanium, iron, and aluminum) and the incorporation of –NH 2 groups in terms of adsorption efficiency against gaseous formaldehyde (FA). A group of the pristine MIL MOFs is synthesized using three different metals (i.e., titanium, iron, and aluminum) and terephthalic acid along with their NH 2 derivatives using 2-aminoterephthalic acid. Among the pristine forms, MIL-125(Ti) achieves the highest FA adsorption capacity (Q) of 26.96 mg g−1 and a partition coefficient (PC) of 0.0898 mol kg−1 Pa−1. Further, amination significantly improves the FA adsorption potential of NH 2 -MIL-125(Ti) with a Q value of 91.22 mg g−1 (PC = 0.3038 mol kg−1 Pa−1). In situ diffuse reflectance infrared Fourier-transform spectroscopy reveals that the FA adsorption of plain MILs should be governed primarily by physisorption. In contrast, FA adsorption of NH 2 -MILs appears to be regulated by both physisorption and chemisorption, while the latter being affected mainly through FA-NH 2 interactions (Schiff base reactions). These findings provide valuable insights into the utility of aminated MIL sorbents, possibly toward the efficient management of indoor air quality. [Display omitted] • MIL MOFs with different central metals and organic ligands were formulated. • Effects of key variables (e.g., formaldehyde concentration and relative humidity) on MIL adsorption were studied. • NH 2 -MIL-125(Ti) was identified as the best performer for FA adsorption. • Chemisorption dominated FA adsorption on aminated MIL MOFs through a Schiff base reaction. [ABSTRACT FROM AUTHOR]

Scientific interest in SOA influence on indoor air quality increases since last 20 years. It is well known, that particles of nano-sized diameter pose a threat for human health causing, among others: eye, upper airway irritation, inflammatory response in cells, worsening asthma, hypertension, diabetes, and central nervous dysfunction. Terpenes are reactive VOCs, commonly emitted in indoor air and considered to be SOA precursors by oxidation reactions. The aim of this study was to investigate the relative humidity influence on i) formation of limonene ozonolysis products and ii) SOA formation process – especially the first steps of it. We managed to determine 4 uncommon limonene ozonolysis products (m / z : 43, 83, 99 and 110) appearing in the PTR-TOF-MS mass spectra with the same frequency as well-known formaldehyde, acetone, acetic acid and formic acid. We also detected m / z 75 and m / z 115 formed under dry conditions and m / z 111 and m / z 125 formed under humid conditions. Detected masses formula is proposed with probability >70 % and the probability is derived from the deviation of the exact mass to the measured one and the isotope distribution. SMPS data analysis allowed us to conclude that RH around 40% increases particle mass concentration, regardless initial limonene concentration. Unfortunately, conclusions about RH influence on particle number concentration are inconsistent. Under low initial terpene concentration, RH around 40% decreases particle number concentration. However, for high initial limonene concentration, RH around 40% caused increase in particle number concentration. Obtained results allowed to conclude, that i) RH influences both particle number and particle mass concentration, ii) initial substrate concentration influences SOA formation altering the RH effect, iii) comparison of results and drawing conclusions is difficult due to different experimental protocols in the literature and due to the number of factors influencing SOA formation initiated by terpene oxidation. [Display omitted] • Specific, uncommon limonene ozonolysis products are formed under dry and humid conditions. • Increased RH increases particle mass concentration regardless initial terpene concentration. • Increased RH causes decrease in particle number concentration for experiments with low initial terpene concentration. • RH influence on particle number concentration is unclear for experimental with high initial terpene concentration. • Substrate concentration influences SOA formation, particle concentration and size distribution over time. [ABSTRACT FROM AUTHOR]

Buildings contaminated with polychlorinated biphenyls (PCBs) are a health concern for the building occupants. Inhalation exposure is linked to indoor air concentrations of PCBs, which are known to be affected by indoor temperatures. In this study, a highly PCB contaminated room was heated to six temperature levels between 20 and 30 C, i.e. within the normal fluctuation of indoor temperatures, while the air exchange rate was constant. The steady-state air concentrations of seven PCBs were determined at each temperature level. A model based on Clausius–Clapeyron equation, ln( P ) = −ΔH/RT + a 0 , where changes in steady-state air concentrations in relation to temperature, was tested. The model was valid for PCB-28, PCB-52 and PCB-101; the four other congeners were sporadic or non-detected. For each congener, the model described a large proportion (R 2 >94%) of the variation in indoor air PCB levels. The results showed that one measured concentration of PCB at a known steady-state temperature can be used to predict the steady-state concentrations at other temperatures under circumstances where e.g. direct sunlight does not influence temperatures and the air exchange rate is constant. The model was also tested on field data from a PCB remediation case in an apartment in another contaminated building complex where PCB concentrations and temperature were measured simultaneously and regularly throughout one year. The model fitted relatively well with the regression of measured PCB air concentrations, ln( P ) vs. 1/ T , at varying temperature between 16.3 and 28.2 °C, even though the measurements were carried out under uncontrolled environmental condition. [ABSTRACT FROM AUTHOR]

Fifteen carbonyl compounds were investigated in the living rooms and bedrooms of 25 university student flats in the urban area of Ciudad Real (Central Southern Spain) in wintertime. Carbonyls were sampled using Radiello ® passive samplers refilled in the laboratory according to the method described in ISO 16000-3 Standard. The most abundant carbonyls in the living rooms and bedrooms were formaldehyde, acetone, acetaldehyde, hexaldehyde and butyraldehyde. The median concentration levels in the living rooms and bedrooms were: 28.6 and 34.2 μg m−3 for formaldehyde, 18.3 and 23.1 μg m−3 for acetone, 14.3 and 15.8 μg m−3 for acetaldehyde, 11.4 and 14.1 μg m−3 for hexaldehyde and 10.8 and 12.4 μg m−3 for butyraldehyde. The median concentration of formaldehyde, benzaldehyde, valeraldehyde and hexaldehyde was significantly higher in the bedrooms than in the living rooms. Indoor concentrations were significantly higher than outdoor concentrations for all carbonyl measured, indicating that sources in the indoor environment are prevailing in all flats. Principal component analysis, multiple linear regressions and Spearman correlation coefficients were used to investigate the origin, the indoor pollutants determinants and to establish common sources between carbonyls. Eight components were extracted from the application of PCA to the indoor and outdoor measurements accounting for 97.7% of the total variance. Formaldehyde, acetone, acetaldehyde and acrolein presented different indoor sources. In the multiple linear regression analysis, higher formaldehyde concentrations were found in those living rooms with wood floor and smoking was positively associated to acetone, propionaldehyde, benzaldehyde and isovaleraldehyde. Formaldehyde, acetaldehyde, acrolein, acetone, propionaldehyde and benzaldehyde concentrations were compared with relevant international guidelines, being their concentrations below recommended values except acrolein, where all measured flats exceeded the reference levels; it would be important to focus on the characterization of emission sources of acrolein in indoor air in order to minimise the exposure and health risk. [Display omitted] • Radiello ® passive samplers refilled in the laboratory can be considered to measure carbonyl compounds in indoor air. • The median concentration of formaldehyde, benzaldehyde, valeraldehyde and hexaldehyde was significantly higher in the bedrooms. • The median concentration levels in bedrooms (µg m-3) were 34.2 for formaldehyde, 23.1 for acetone and 15.8 for acetaldehyde. • Indoor sources in university student flats played a decisive role in the concentrations of all measured carbonyls. • All the carbonyls levels are below recommended indoor air quality guidelines except acrolein. [ABSTRACT FROM AUTHOR]

Abstract: The photocatalytic elimination of microorganisms from indoor air in realistic conditions and the feasibility of simultaneous elimination of chemical contaminants have been studied at laboratory scale. Transparent polymeric monoliths have been coated with sol–gel TiO2 films and used as photocatalyst to treat real indoor air in a laboratory-scale single-step annular photocatalytic reactor. The analytical techniques used to characterize the air quality and analyze the results of the photocatalytic tests were: colony counting, microscopy and PCR with subsequent sequencing for microbial quantification and identification; automated thermal desorption coupled to gas chromatography with mass spectrometry detection for chemical analysis. The first experiments performed proved that photocatalysis based on UVA-irradiated TiO2 for the reduction of the concentration of bacteria in the air could compete with the conventional photolytic treatment with UVC radiation, more expensive and hazardous. Simultaneously to the disinfection, the concentration of volatile organic compounds was greatly reduced, which adds value to this technology for real applications. The fungal colony number was not apparently modified. [Copyright &y& Elsevier]

As many people spend a large part of their life indoors, the quality of the indoor environment is important. Data on contaminants such as flame retardants, pesticides and plasticizers are available for indoor air and dust but are scarce for consumer products such as computers, televisions, furniture, carpets, etc. This review presents information on semi-volatile organic compounds (SVOCs) in consumer products in an attempt to link the information available for chemicals in indoor air and dust with their indoor sources. A number of 256 papers were selected and divided among SVOCs found in consumer products (n = 57), indoor dust (n = 104) and air (n = 95). Concentrations of SVOCs in consumer products, indoor dust and air are reported (e.g. PFASs max: 13.9 μg/g in textiles, 5.8 μg/kg in building materials, 121 ng/g in house dust and 6.4 ng/m 3 in indoor air). Most of the studies show common aims, such as human exposure and risk assessment. The main micro-environments investigated (houses, offices and schools) reflect the relevance of indoor air quality. Most of the studies show a lack of data on concentrations of chemicals in consumer goods and often only the presence of chemicals is reported. At the moment this is the largest obstacle linking chemicals in products to chemicals detected in indoor air and dust. [ABSTRACT FROM AUTHOR]

Air pollution in China is an ongoing concern, with subsets of the population (e.g., asthmatic children) especially susceptible to the associated health effects. In addition, people spend the majority of their time indoors, where pollutant composition may differ from the better characterized ambient environment. Although volatile organic compounds (VOCs) present health risks and have high concentrations indoors, their sources have not been thoroughly quantified in typical homes in suburban China. Similarly lacking is an understanding of how well a purifier with high efficiency particulate air and activated carbon filters can remove VOCs in a real-world setting in China. In this study, we a) quantified total VOCs (TVOC) and 900 + individual VOCs in 20 homes in China, b) identified potential sources of VOCs, and c) evaluated impacts of filtration. We used non-negative matrix factorization, a variable reduction technique, to identify sources. TVOC and individual compounds had higher concentrations indoors than outdoors (mean [range] indoors, filtration with pre-filter only: 302 [56–793] μg m−3; outdoors, entire study: 92 [26–629] μg m−3), indicating prevalent sources indoors. Many compounds detected have not, to our knowledge, been measured in homes in China. Some compounds (e.g., octanal, heptanal, ⍺-cedrene) were specific to the indoor environment, a few were ubiquitous (e.g., acetaldehyde, formaldehyde), and others were detected infrequently. These compounds may originate from consumer products, solvents, vehicle emissions, a hexane source, wooden products, and cooking. Filtration may improve air quality indoors by lowering concentrations of some VOCs, and, specifically, contributions related to solvents and consumer products. Image 1 • Volatile organic compounds, many of which pose health risks to humans, are prevalent indoors. • We quantified 900 + VOCS/aldehydes in 20 homes in suburban Shanghai. • Sources of VOCs were identified using non-negative matrix factorization. • Use of an air purifier may reduce concentrations of some VOCs in the home. [ABSTRACT FROM AUTHOR]