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2. Mechanistic Details and Conformational Behavior of Selective Peptide Linkage Facilitated by Aun Clusters.

Author

Yadav, Sarita, Springborg, Michael, Singhal, Sonal, Molayem, Mohammad, and Goel, Neetu

Subjects
ALANINE, GOLD clusters, AMINO acids, DENSITY functional theory, PEPTIDE synthesis, METAL clusters
Abstract

The interactions of amino acids Glycine and Alanine with gold clusters, Aun (n=3, 8, 16) have been studied in both gas and aqueous phase within the formalism of density functional theory (DFT). The amino acid binds to the cluster with its amine/carboxyl end securely anchored to the cluster. Selective peptide synthesis has been explored for Glycylglycine (GlyGly) and Glycylalanine (GlyAla) dipeptides in aqueous medium via two different reaction pathways. Path‐ [ABSTRACT FROM AUTHOR]

Published
2020
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