Search

Your search keyword '"Mitsuko Shibuya"' showing total 1 results
Start Over Author "Mitsuko Shibuya" Journal chemistry letters
1 results on '"Mitsuko Shibuya"'

1. Thermal and Photochemical Formation of Dinuclear Molybdenadithiolene Complexes in One-Pot Reactions among[(Cp)2Mo2(CO)6], Elemental Sulfur and Dimethyl Acetylenedicarboxylate

Author

Akira Sugimori, Risa Nakase, Tatsuya Yamanaka, Mitsuko Shibuya, Masatsugu Kajitani, Takeo Akiyama, and Toru Sugiyama

Subjects
Dimethyl acetylenedicarboxylate, chemistry.chemical_compound, chemistry, Decarbonylation, Thermal, chemistry.chemical_element, General Chemistry, Thermal reaction, Photochemistry, Sulfur
Abstract

One-pot reaction among [(Cp)2Mo2(CO)6], elemental sulfur, and dimethyl acetylenedicarboxylate (DMAD) affords several types of dinuclear molybdenadithiolene complexes. The thermal reaction gives [(Cp)(CO)2Mo{μ-S2C2(CO2Me)2}2Mo(Cp)] (2), while the photoreaction gives mainly isomeric [(Cp)Mo(CO){μ-S2C2(CO2Me)2}2Mo(CO)(Cp)] (3). The former dicarbonylmolybdenum complex easily undergoes decarbonylation, while the latter is thermally stable.

Published
1998
Full Text
View/download PDF

Catalog

Books, media, physical & digital resources
See catalog results