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Start Over Author "Hirofumi Kosuge" Journal chemistry letters
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1. Mechanical Stirring Speed in Water/Hexane Biphasic Catalyst Controls Regioselectivity of Pd-catalyzed Allylation Reaction

Author

Masafumi Hirano, Hirofumi Kosuge, Akari Sako, Nobuyuki Komine, and Sanshiro Komiya

Subjects
Steric effects, organic chemicals, Mixing (process engineering), food and beverages, Regioselectivity, General Chemistry, Medicinal chemistry, Catalysis, Hexane, chemistry.chemical_compound, chemistry, Organic chemistry, Reactivity (chemistry), Allyl Sulfide
Abstract

Vigorous mechanical mixing of the water/hexane biphasic Pd-catalyzed allylation of benzenethiol gave sterically congested allyl sulfides, due to high reactivity of the enforced orientation of the η...

Published
2008

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