Search

Your search keyword '"Goulven Cosquer"' showing total 2 results
Start Over Author "Goulven Cosquer" Journal chemistry letters
2 results on '"Goulven Cosquer"'

1. Formation of Pores and π-Stacked Columns in Benzothienobenzothiophene-based Linear Coordination Polymers

Author

Hiroaki Iguchi, Goulven Cosquer, Toshihiro Okamoto, Jun Takeya, Masahiro Yamashita, Shohei Kumagai, Shinya Takaishi, and Shohei Koyama

Subjects
chemistry.chemical_classification, chemistry.chemical_compound, chemistry, 010405 organic chemistry, Coordination polymer, Polymer chemistry, Benzothiophene, General Chemistry, Polymer, 010402 general chemistry, Porosity, 01 natural sciences, 0104 chemical sciences
Abstract

Porous coordination polymer (PCP) with 2,7-bis(4-pyridyl)-[1]benzothieno[3,2-b][1]benzothiophene (BTBT-4py) ligands was synthesized. The PCP provides both pores and infinite π-stacked columns via t...

Published
2019
Full Text
View/download PDF

2. Formation of Pores and p-Stacked Columns in Benzothienobenzothiophene-based Linear Coordination Polymers.

Author

Shohei Koyama, Hiroaki Iguchi, Shinya Takaishi, Goulven Cosquer, Shohei Kumagai, Jun Takeya, Toshihiro Okamoto, and Masahiro Yamashita

Abstract

Porous coordination polymer (PCP) with 2,7-bis(4-pyridyl)-[1]benzothieno[3,2-b][1]benzothiophene (BTBT-4py) ligands was synthesized. The PCP provides both pores and infinite π-stacked columns via the assemblies of linear coordination polymers. The overlap integrals between highest occupied molecular orbitals (HOMOs) of adjacent ligands largely depend on the conformation of BTBT cores. The PCP also showed drastic structural change induced by desolvation. This approach to introduce porosity in organic semiconductor crystal can lead to the development of molecular-based devices, such as porous field-effect transistor. [ABSTRACT FROM AUTHOR]

Published
2019
Full Text
View/download PDF

Catalog

Books, media, physical & digital resources
See catalog results