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1. A General and Selective Rhodium-Catalyzed Reduction of Amides, N-Acyl Amino Esters, and Dipeptides Using Phenylsilane.

Author

Das, Shoubhik, Li, Yuehui, Lu, Liang‐Qiu, Junge, Kathrin, and Beller, Matthias

Subjects
*REDUCTION of amides, *RHODIUM catalysts, *CATALYSIS, *CHEMICAL reduction, *CHEMOSELECTIVITY, *MOIETIES (Chemistry)
Abstract

This article describes a selective reduction of functionalized amides, including N-acyl amino esters and dipeptides, to the corresponding amines using simple [Rh(acac)(cod)]. The catalyst shows excellent chemoselectivity in the presence of different sensitive functional moieties. [ABSTRACT FROM AUTHOR]

Published
2016
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