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Group 16 chalcogens potentially provide Lewis‐acidic σ‐holes, which are able to form attractive supramolecular interactions with electron rich partners through chalcogen bonds. Here, a multifaceted experimental and computational study of a large series of novel chalcogen‐bonded cocrystals, prepared using the principles of crystal engineering, is presented. Single‐crystal X‐ray diffraction studies reveal that dicyanoselenadiazole and dicyanotelluradiazole derivatives work as promising supramolecular synthons with the ability to form double chalcogen bonds with a wide range of electron donors including halides and oxygen‐ and nitrogen‐containing heterocycles. Extensive 77Se and 125Te solid‐state nuclear magnetic resonance spectroscopic investigations of cocrystals establish correlations between the NMR parameters of selenium and tellurium and the local chalcogen bonding geometry. The relationships between the electronic environment of the chalcogen bond and the 77Se and 125Te chemical shift tensors were elucidated through a natural localized molecular orbital density functional theory analysis. This systematic study of chalcogen‐bond‐based crystal engineering lays the foundations for the preparation of the various multicomponent systems and establishes solid‐state NMR protocols to detect these interactions in powdered materials. [ABSTRACT FROM AUTHOR]

Frontispiece: Double Chalcogen Bonds: Crystal Engineering Stratagems via Diffraction and Multinuclear Solid-State Magnetic Resonance Spectroscopy Keywords: chalcogen bonds; crystal engineering; dicyanoselenadiazole; dicyanotelluradiazole; molecular orbital analysis; solid-state NMR Chalcogen bonds, crystal engineering, dicyanoselenadiazole, dicyanotelluradiazole, molecular orbital analysis, solid-state NMR. [Extracted from the article]