Search

Transition‐metal borides (TMBs) containing Bn‐fragment (n>3) have recently gained interest for their ability to enable exciting magnetic materials. Herein, we show that the B4‐containing TiFe0.64(1)Os2.36(1)B2 is a new ferromagnetic TMB with a Curie temperature of 523(2) K and a Weiss constant of 554(3) K, originating from the chain of M3‐triangles (M=64 %Fe+36 %Os). The new phase was synthesized from the elements by arc‐melting, and its structure was elucidated by single‐crystal X‐ray diffraction. It belongs to the Ti1+xOs2−xRuB2‐type structure (space group P6‾ 2 m, no. 189) and contains trigonal‐planar B4 boron fragments [B−B distance of 1.87(4) Å] interacting with M3‐triangles [M–M distances of 2.637(8) Å and 3.0199(2) Å]. The experimental results were supported by computational calculations based on the ideal TiFeOs2B2 composition, which revealed strong ferromagnetic interactions within and between the Fe3‐triangles. This discovery represents the first magnetically ordered Os‐rich TMB, thus it will help expand our knowledge of the role of Os in low‐dimensional magnetism of intermetallics and enable the design of such materials in the future. [ABSTRACT FROM AUTHOR]

Transition‐metal borides (TMBs) containing Bn‐fragment (n>3) have recently gained interest for their ability to enable exciting magnetic materials. Herein, we show that the B4‐containing TiFe0.64(1)Os2.36(1)B2 is a new ferromagnetic TMB with a Curie temperature of 523(2) K and a Weiss constant of 554(3) K, originating from the chain of M3‐triangles (M=64 %Fe+36 %Os). The new phase was synthesized from the elements by arc‐melting, and its structure was elucidated by single‐crystal X‐ray diffraction. It belongs to the Ti1+xOs2−xRuB2‐type structure (space group P6‾ 2 m, no. 189) and contains trigonal‐planar B4 boron fragments [B−B distance of 1.87(4) Å] interacting with M3‐triangles [M–M distances of 2.637(8) Å and 3.0199(2) Å]. The experimental results were supported by computational calculations based on the ideal TiFeOs2B2 composition, which revealed strong ferromagnetic interactions within and between the Fe3‐triangles. This discovery represents the first magnetically ordered Os‐rich TMB, thus it will help expand our knowledge of the role of Os in low‐dimensional magnetism of intermetallics and enable the design of such materials in the future. [ABSTRACT FROM AUTHOR]