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Electrons communicate with each other via the “magpie bridge” made by secondary forces. A series of conjugation ‐ interrupted dipyridyl ‐ linked Te−Fe−Cu carbonyl cluster ‐ incorporated polymers have been synthesized by liquid ‐ assisted grinding. These polymers exhibit surprising semiconducting characteristics with ultra ‐ narrow bandgaps and high conductivities, attributed to the through ‐ space electron transport via non ‐ classical C−H⋅⋅⋅O(carbonyl) hydrogen bonds and aromatic C−H⋅⋅⋅π interactions. More information can be found in the Full Paper by M. Shieh, H. ‐ L. Liu et al. on page 11261. [ABSTRACT FROM AUTHOR]