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Start Over Author "Qi-Zhi Ren" Journal chemistry (weinheim an der bergstrasse, germany)
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1. A unique binaphthyl strapped iron-porphyrin catalyst for the enantioselective epoxidation of terminal olefins

Author

Qi-Zhi Ren, Bruno Andrioletti, and Eric Rose

Subjects
chemistry.chemical_compound, chemistry, Organic Chemistry, Enantioselective synthesis, Organic chemistry, General Chemistry, Enantiomer, Chirality (chemistry), Porphyrin, Medicinal chemistry, Catalysis, Styrene
Abstract

A new chiral binaphthyl-strapped iron-porphyrin 4 b that exhibits unprecedented catalytic activity toward the enantioselective epoxidation of terminal olefins was synthesized. Typical enantiomeric excesses (ee) of 90 % were measured with a maximum of 97 % for the epoxidation of styrene, whereas the turnover numbers (TON) averaged 16000.

Published
2003

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