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Start Over Author "Agonist Kastrati" Journal chemistry (weinheim an der bergstrasse, germany)
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1. Reliable Functionalization of 5,6-Fused Bicyclic N-Heterocycles Pyrazolopyrimidines and Imidazopyridazines via Zinc and Magnesium Organometallics

Author

Saroj Kumar Rout, Agonist Kastrati, Harish Jangra, Kuno Schwärzer, Alisa S. Sunagatullina, Maximilien Garny, Fabio Lima, Cara E. Brocklehurst, Konstantin Karaghiosoff, Hendrik Zipse, and Paul Knochel

Subjects
Zinc, Pyrimidines, Organic Chemistry, Indicators and Reagents, Magnesium, General Chemistry, Catalysis
Abstract

DFT-calculations allow prediction of the reactivity of uncommon N-heterocyclic scaffolds of pyrazolo[1,5-a]pyrimidines and imidazo[1,2-b]pyridazines and considerably facilitate their functionalization. The derivatization of these N-heterocycles was realized using Grignard reagents for nucleophilic additions to 5-chloropyrazolo[1,5-a]pyrimidines and TMP

Published
2022

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