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Start Over Author "B. Hickey" Journal chemischer informationsdienst
6 results on '"B. Hickey"'

1. ChemInform Abstract: SELECTIVITY IN VINYL AZIDE REACTIONS: DECOMPOSITION OF AZIDOCINNAMATES WITH OLEFINIC ORTHO SUBSTITUENTS

Author

Charles W. Rees, Deirdre M. B. Hickey, and Christopher J. Moody

Subjects
chemistry.chemical_compound, Degree of unsaturation, Benzazepines, chemistry, Thermal decomposition, Substituent, General Medicine, Azide, Selectivity, Medicinal chemistry, Decomposition
Abstract

Thermal decomposition of vinyl azides (1a–c) gives isoquinolines (3), benzazepines (4), or aziridines (5) and (6) by preferential reaction at the unsaturated substituent; removal of this unsaturation as in the epoxides (1d,1e) leads exclusively to 4-substituted indoles.

Published
1983
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4. ChemInform Abstract: PHOTOLYSIS OF AZIDOCINNAMATES: ISOLATION OF AZIRINE TRIMERS. X-RAY CRYSTAL STRUCTURE OF TRIETHYL 2,4,9-TRI-O-TOLYL-1,3,8-TRIAZATRICYCLO(4.3.0.03,5)NON-7-ENE-5,6,7-TRICARBOXYLATE

Author

David J. Williams, Charles W. Rees, Christopher J. Moody, and Deirdre M. B. Hickey

Subjects
Azirine, chemistry.chemical_compound, Chemistry, Photodissociation, X-ray, General Medicine, Crystal structure, Radiation chemistry, Medicinal chemistry, Tricarboxylate, Ene reaction
Abstract

Photolysis of the azidocinnamates (1) gives trimers of the azirines (2); X-ray crystallographic analysis establishes the triazatricyclononene structure (6) for these trimers.

Published
1982
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5. ChemInform Abstract: SYNTHESIS OF ISOQUINOLINES FROM AZIDOCINNAMATES: THE EFFECT OF IODINE

Author

Deirdre M. B. Hickey, Christopher J. Moody, and Charles W. Rees

Subjects
Chemistry, Thermal decomposition, chemistry.chemical_element, Organic chemistry, General Medicine, Iodine, Catalytic effect
Abstract

Iodine has a marked catalytic effect on the thermolysis of azidocinnamates; indoles, isoquinolines, 1,2-dihydroisoquinolines, or enamines are isolated depending on the conditions.

Published
1982
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