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3. ChemInform Abstract: Transformation of 4-Nitroalkane-1,7-diones into Pyrrolizidines

Author

Manfred Hesse, M. Vavrecka, and A. Janowitz

Subjects
Transformation (genetics), Xenovenine, Chemistry, Nitroalkane, General Medicine, Medicinal chemistry
Abstract

Depending on the conditions the reduction of 5-nitropentadecane-2,8-dione ( 4 ) gave as main products the two isomeric pyrrolizidines 1a (xenovenine, NaBH 3 CN/NH 4 OAc; as 15 N- 1a with NaBH 3 CN/ 15 NH 4 OAc) and 1b (H 2 -Pd/C), respectively.

Published
2010
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