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5. ChemInform Abstract: Outer-Sphere Association of Calixarenes and Other Macrocyclic Ligands with Metal Complexes as the Basis for the Design of Molecular Devices

Author

V. V. Skripacheva, Asiya R. Mustafina, and Alexander I. Konovalov

Subjects
genetic structures, Chemistry, Association (object-oriented programming), Solid-state, General Medicine, Basis (universal algebra), equipment and supplies, Metal, Crystallography, visual_art, Calixarene, visual_art.visual_art_medium, Outer sphere electron transfer, sense organs
Abstract

The regular features of the formation of outer-sphere associates of water-soluble calixarenes with metal complexes in solutions and their structure in the solid state are analysed. A comparison with analogous data for other outer-sphere macrocyclic ligands is carried out. Some physicochemical properties of the outer-sphere associates are considered in regards to their potential use for the development of new processes and materials.

Published
2008
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7. New Ligands for Enantioselective Recognition of Chiral Carboxylates Based on 1,1′-Binaphthalene-2,2′-diamine

Author

Asiya R. Mustafina, Ivan Stibor, Roman Holakovský, and Pavel Lhoták

Subjects
chemistry.chemical_compound, Axial chirality, Chemistry, Diamine, Enantioselective synthesis, Organic chemistry, General Chemistry, General Medicine, Optically active, Combinatorial chemistry
Abstract

Simple bis(arylureido)binaphthalenes and (arylamido)binaphthalenes have been synthesized in both racemic as well as optically active forms. One of these compounds has been found to complex chiral anions with modest enantioselectivity.

Published
2004
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