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5. ChemInform Abstract: Catalytic Arylation of Carbon-Carbon Double Bond Followed by N- or O-Cyclization

Author

A. Del Rio and M. Catellani

Subjects
inorganic chemicals, chemistry.chemical_classification, Double bond, Aryl, Reinforced carbon–carbon, chemistry.chemical_element, General Medicine, Ring (chemistry), Catalysis, chemistry.chemical_compound, chemistry, Polymer chemistry, Organic chemistry, Carbon, Phosphine, Palladium
Abstract

Under the catalytic action of palladium,o-hydroxy- oro-amino-substituted aryl iodides oxidatively add to palladium(0), insert strained or rigid olefins, and close the ring between the aliphatic carbon and theortho-functional group. This reaction occurs under mild conditions in the absence of phosphine ligands in a DMF solution and affords fused dihydrofurans or-pyrroles.

Published
2010
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