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2. Ring Opening of 3-Bromo-2-isoxazolines to ?-Hydroxy Nitriles

Author

Martin G. Kociolek and Kyle P. Kalbarczyk

Subjects
chemistry.chemical_classification, chemistry.chemical_compound, chemistry, Sodium iodide, General Medicine, Bridged compounds, Ring (chemistry), Medicinal chemistry
Abstract

3‐Bromo‐2‐isoxazolines were converted to the corresponding β‐hydroxy nitriles by treatment with sodium iodide in the presence of either chlorotrimethylsilane or para‐toluenesulfonic acid. Both methods gave β‐hydroxy nitriles under relatively mild conditions in good to moderate yields for a variety of substituted 3‐bromo‐2‐isoxazolines.

Published
2005
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