Search

Your search keyword '"K. A. Gavrilov"' showing total 10 results
Start Over Author "K. A. Gavrilov" Journal cheminform
10 results on '"K. A. Gavrilov"'

1. ChemInform Abstract: Phosphorodiamidite Derivatives of 1,1′-Bi-2-naphthol Containing Stereogenic Phosphorus Atoms as Ligands in Enantioselective Catalysis

Author

A. S. Safronov, E. A. Rastorguev, Vadim A. Davankov, S. V. Zheglov, M. G. Maksimova, A. A. Shiryaev, P. V. Petrovskii, Manfred T. Reetz, N. N. Groshkin, and K. N. Gavrilov

Subjects
Allylic rearrangement, organic chemicals, 1,1'-Bi-2-naphthol, Phosphorus, Enantioselective synthesis, food and beverages, chemistry.chemical_element, General Medicine, Medicinal chemistry, Stereocenter, Catalysis, Tsuji–Trost reaction, chemistry.chemical_compound, chemistry, Amination
Abstract

Two new chiral binaphthol derivatives are synthesized and used as ligands in transition metal-catalyzed hydrogenation, allylic alkylation and allylic amination reaction.

Published
2011
Full Text
View/download PDF

2. ChemInform Abstract: Enantioselective Metal Complex Catalysis. Part 6. Rhodium Catalysts of Asymmetric Hydrosilylation Based on Chiral Phosphites

Author

K. N. Gavrilov, E. I. Klabunovskii, V. A. Pavlov, E. E. Nifant'ev, E. Yu. Zhorov, L. S. Gorshkova, and A. T. Teleshev

Subjects
Metal, Addition reaction, chemistry.chemical_compound, chemistry, Hydrosilylation, visual_art, Enantioselective synthesis, visual_art.visual_art_medium, chemistry.chemical_element, Organic chemistry, General Medicine, Rhodium, Catalysis
Published
2010
Full Text
View/download PDF

6. ChemInform Abstract: Chiral Phosphorous Acid Derivatives in the Synthesis of Coordination Compounds and in Homogeneous Asymmetric Catalysis. Complexes with P-Monodentate and P,N-Bidentate Ligands

Author

K. N. Gavrilov and Igor S. Mikhel

Subjects
chemistry.chemical_classification, chemistry.chemical_compound, Denticity, chemistry, Stereochemistry, Homogeneous, Polymer chemistry, Enantioselective synthesis, General Medicine, Phosphorous acid, Coordination complex
Published
2010
Full Text
View/download PDF

10. ChemInform Abstract: Chiral P,N-Bidentate Ligands in Coordination Chemistry and Organic Catalysis Involving Rhodium and Palladium

Author

K. N. Gavrilov and A. I. Polosukhin

Subjects
chemistry.chemical_classification, Allylic rearrangement, Hydrosilylation, Enantioselective synthesis, chemistry.chemical_element, General Medicine, Rhodium, Coordination complex, Catalysis, Hydroboration, chemistry.chemical_compound, chemistry, Polymer chemistry, Palladium
Abstract

Published data on the synthesis of rhodium and palladium complexes with optically active P,N-bidentate ligands and their applications in homogeneous asymmetric catalysis are summarised and discussed. The effect of the nature of the P,N-bidentate compounds on the structure of the metal complexes and on enantioselectivity in catalysis is examined. Allylic substitution, cross-coupling, hydroboration and hydrosilylation catalysed by Rh or Pd complexes with optically active P,N-bidentate ligands are considered. The prospects for the development of this field of chemistry are demonstrated. The bibliography includes 186 references.

Published
2001
Full Text
View/download PDF

Catalog

Books, media, physical & digital resources
See catalog results