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2. ChemInform Abstract: Efficient Aromatic and Heteroatom Acylations Using Catalytic Indium Complexes with Lithium Perchlorate

Author

Christopher G. Frost, Alan John Whittle, Christopher J. Chapman, and Joseph P. Hartley

Subjects
Chemistry, digestive, oral, and skin physiology, Heteroatom, chemistry.chemical_element, General Medicine, respiratory system, Lithium perchlorate, Catalysis, Isopropenyl acetate, Acylation, chemistry.chemical_compound, Acetone, Organic chemistry, lipids (amino acids, peptides, and proteins), Indium
Abstract

The combination of an indium complex with lithium perchlorate affords a potent system for the catalytic acylation of electron-rich aromatics and alcohols. The use of isopropenyl acetate as acyl donor results in cleaner methodology with acetone as the only by-product. The study has also revealed an indium-catalysed ketalisation reaction.

Published
2001

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