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1. ChemInform Abstract: Phosphorescence from the Triplet Spin Sublevels of a Hexanuclear Molybdenum(II) Chloride Cluster Ion, (Mo6Cl14)2-. Relative Radiative Rate Constants for Emitting Sublevels

Author

Yoichi Sasaki, Takeshi Ikeyama, Hisayuki Miki, and T. Azumi

Subjects
chemistry.chemical_compound, Reaction rate constant, Chemistry, Radiative transfer, Cluster (physics), Molybdenum(II) chloride, General Medicine, Spectral shift, Atomic physics, Phosphorescence, Photochemistry, Spin (physics), Ion
Abstract

Phosphorescence of [Mo 6 Cl 14 ] 2- is investigated focusing attention on the temperature-dependent spectral shift. The relative radiative rate constants for the emitting sublevels T 2u , E u , and T 1u are 1:5:8:100. The large radiative rate constant for the T 1u sublevel substantiates the previous assignment of the sublevels

Published
2010

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