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A steady state concentration of HSNO is obtained using a gaseous mixture of 1% NO and 0.1% H2S in Ne by supersonic expansion into a cavity through a pulsed valve at 25 °C. [ABSTRACT FROM AUTHOR]

Flash vacuum pyrolysis of MeOS(O)2N3 (caution: potentially hazardous and explosive) results in the formation of HNSO2 in the gas phase. [ABSTRACT FROM AUTHOR]

Single crystals of the title amidozincate of several centimeters in dimensions are grown under ammonothermal conditions in the cold temperature zone of an autoclave using Zn powder and CsNH2 in a 1:2 molar ratio (stainless steel autoclave, 523→≈423 K, 155 MPa, 12 h). [ABSTRACT FROM AUTHOR]

Polycrystalline Ho2W3O12 is prepared by calcination of stoichiometric amounts of Ho2O3 and WO3 in air (1100 °C, 10 h) with different cooling treatments (850 °C plus furnace cooling or 1100 °C plus quenching in H2O) to probe the relationship between phase formation and preparative conditions. [ABSTRACT FROM AUTHOR]

The first catalytic asymmetric aminotrifluoromethylation of alkenes by using Togni′s reagent (II) has been developed. [ABSTRACT FROM AUTHOR]

Ln(BH4)3 (Ln: La, Ce) is synthesized from mixtures of LnCl3 and LiBH4 in toluene (25 °C, 72 h). [ABSTRACT FROM AUTHOR]

Li3BO3 is prepared by ball milling of an equimolar mixture of LiH and LiBO2 followed by vacuum heating of the pelletized material (600 °C, 2 h). [ABSTRACT FROM AUTHOR]

The title perhydridopolysilathianes are prepared by transsilylation and condensation of HSiCl3·2Py with a five-fold stoichiometric excess of gaseous Tms2S and Py (Schlenk vessel at reduced pressure, 55 °C, 4 d) and subsequent calcination (200 °C, vacuum, 2 h). [ABSTRACT FROM AUTHOR]

Review: 262 refs. [ABSTRACT FROM AUTHOR]

Review: 306 refs. [ABSTRACT FROM AUTHOR]

SinH2n+2 (n ≤ 19) is synthesized by irradiation of thin SiH4 films deposited on a cold (5.5 K) Rh-coated Ag wafer with 5 keV electrons (8-60 min) under ultra-high vacuum conditions. [ABSTRACT FROM AUTHOR]

Review: 143 refs. [ABSTRACT FROM AUTHOR]

Energetic and structural stability of Al2B2H2n (n = 0-6) clusters is investigated by DFT calculations and a stochastic search algorithm. [ABSTRACT FROM AUTHOR]

Compounds (IV) and (V) are characterized by single crystal XRD and UV/VIS spectroscopy. [ABSTRACT FROM AUTHOR]

Four stable two-dimensional boron hydride sheets (C2/m, Pbcm, Cmmm, and Pmmn) are identified by DFT calculations and global minimum search with the particle-swarm optimization method. [ABSTRACT FROM AUTHOR]

The UV/VIS absorption spectra of water, ethanol, chloroform, DMF, and DMSO are measured. [ABSTRACT FROM AUTHOR]

Review: 331 refs. [ABSTRACT FROM AUTHOR]

Review: 102 refs. [ABSTRACT FROM AUTHOR]

Review: 144 refs. [ABSTRACT FROM AUTHOR]

Review: 453 refs. [ABSTRACT FROM AUTHOR]

Review: 362 refs. [ABSTRACT FROM AUTHOR]

Co2P nanoparticles are obtained by ball milling (600 rpm, 6 h) of stoichiometric amounts of Co and red P under argon. [ABSTRACT FROM AUTHOR]

Review: 460 refs. [ABSTRACT FROM AUTHOR]

Review: 528 refs. [ABSTRACT FROM AUTHOR]

Review: 189 refs. [ABSTRACT FROM AUTHOR]

The title compounds are prepared from mixtures of ball milled MH2 (M: Sr, Ba, Eu) and excess Et3NBH3 (100 °C for 24 h and 145 °C for 5 h). [ABSTRACT FROM AUTHOR]

Formation of [NH4][BH3NH2BH3] by metathesis reaction between Na(BH3NH2BH3) and NH4SCN in a 1:1 molar ratio in THF at -18 °C is monitored by 11B NMR spectroscopy. [ABSTRACT FROM AUTHOR]

Crystal structures based on powder XRD and hydrogenation properties of 24 Pd-rich intermetallics are presented. [ABSTRACT FROM AUTHOR]

Review: 90 refs. [ABSTRACT FROM AUTHOR]

The layered compound HTi2NbO7 is prepared by solid state reaction of TiO2, Nb2O5, and Cs2CO3 (1373 K, 12 h) and subsequent proton exchange (addition of HCl, 333 K, 24 h). [ABSTRACT FROM AUTHOR]

The structure and bonding of the new title compounds are characterized by powder XRD, neutron diffraction, inelastic neutron scattering, and DFT calculations. [ABSTRACT FROM AUTHOR]

The study of an all-solid-state TiH2/orthorhombic-La2LiHO3/Ti cell provides conclusive evidence of pure H- conduction. [ABSTRACT FROM AUTHOR]

Li2Al(ND2)4BH4 is obtained by ball milling of 1:2 molar mixtures of LiAl(ND2)4 (or NaAl(ND2)4) and LiBH4 under 0.1 MPa Ar. [ABSTRACT FROM AUTHOR]

Selective conversion of N2 into NH3 is achieved through plasmon-induced charge separation by a SrTiO3 photoelectrode loaded with Au nanoparticles and a Zr/ZrOx thin film. [ABSTRACT FROM AUTHOR]

Direct synthesis of H2O2 from H2 and O2 represents an efficient alternative to the current industrial indirect process via sequential hydrogenation and oxidation of a substituted anthraquinone. [ABSTRACT FROM AUTHOR]

At ultrahigh pressure (<110 GPa), H2S is converted into a metallic phase that becomes superconducting with a Tc of ≈200 K. [ABSTRACT FROM AUTHOR]

Single crystals of ZnF2(NH3)3 (I) are prepared by ammonothermal reaction of ZnF2, Zn, NH4F, and NH3 (autoclave, 250 °C, 196 MPa). [ABSTRACT FROM AUTHOR]

AnGd(BH4)n+3 (A: K, Cs) are prepared by ball milling of appropriate amounts of alkali borohydrides and Gd(BH4)3 under an inert atmosphere (600 rpm, 2 min, 60 repetitions; 5 min cooling break). [ABSTRACT FROM AUTHOR]

Li4(NH2)3Cl is prepared by ball milling of a stoichiometric mixture of LiNH2 and LiCl (400 rpm, 5 h) followed by ball milling with LiH to form a composite. [ABSTRACT FROM AUTHOR]

CaNH shows a strong synergistic effect on Mn6N5 in catalyzing the decomposition of NH3. [ABSTRACT FROM AUTHOR]

Single phase Pd5As is prepared by heating stoichiometric amounts of the elements (evacuated silica tubes, 973 K, 4 d). [ABSTRACT FROM AUTHOR]

A new phase of SnH4 with C2/m symmetry is predicted by first-principle calculations using the Vienne ab initio simulation package (VSAP code) at pressures <400 GPa. [ABSTRACT FROM AUTHOR]

Stable β-PdH0.43 nanocrystals are produced by heating a Pd(acac)2 solution in DMF (160 °C, 4 h) using the in situ H2 production from catalytic decomposition of the latter. [ABSTRACT FROM AUTHOR]

Review: [emphasis on metal amides, alanates and borohydrides; 45 refs. [ABSTRACT FROM AUTHOR]

Bi[B12H12]·3H2O (I) and Bi[B12H12]·6H2O (II) are obtained by dehydration of an aqueous mixture of Bi2O3(CO3) and (H3O)[B12H12] at 40 °C. [ABSTRACT FROM AUTHOR]

α-Mn(BH4)2 is prepared by high-energy ball milling of stoichiometric amounts of LiBH4 and MnCl2 or by metathesis reaction of the latter precursors in Et2O to yield NaMn2(BH4)2·2Et2O followed by desolvation under vacuum at 110 °C. [ABSTRACT FROM AUTHOR]

NdGaH1.66 and its deuterated analogue are obtained by heating NdGa with H2 or D2 (autoclave, 10-20 bar, 300 °C, up to 48 h) and characterized by powder neutron diffraction, thermal desorption mass spectrometry, and magnetic measurements. [ABSTRACT FROM AUTHOR]

BaTiO2.5H0.5 (I) is used as a starting material in multistep low temperature topochemical routes to access mixed anion compounds. [ABSTRACT FROM AUTHOR]

Review: [40 refs. [ABSTRACT FROM AUTHOR]

Review: 69 refs. [ABSTRACT FROM AUTHOR]