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1. ChemInform Abstract: 1-Phosphabarrelene Complexes of Palladium and Their Use in Suzuki-Miyaura Coupling Reactions

Author

Matthias Blug, Nicolas Mézailles, Clément Guibert, Xavier-Frédéric Le Goff, and Pascal Le Floch

Subjects
Coupling (electronics), chemistry.chemical_compound, chemistry, Aryl, Polymer chemistry, chemistry.chemical_element, General Medicine, Phenylboronic acid, Aryne, Coupling reaction, Palladium, Catalysis
Abstract

A bulky 1-phosphabarrelene, 2, was obtained from the reaction of a phosphinine with benzyne; two palladium complexes of 2 were successfully employed in the Suzuki–Miyaura coupling of several aryl chlorides with phenylboronic acid at a relatively low catalyst loading, and activated aryl chlorides were coupled at room temperature in the absence of strong bases.

Published
2009
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