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1. ChemInform Abstract: A New Entry to 1,5-Keto Esters and Their 4,4-Dideuterio Derivatives via Methylene Chloride as 'Methylene Dianion' Equivalents

Author

Tu-Hsin Yan, Cheng-Yih Chen, Wei-Fan Chen, and Kuo-Wei Lin

Subjects
chemistry.chemical_compound, Chemistry, medicine, General Medicine, Methylene, Methyl acrylate, Chloride, Medicinal chemistry, medicine.drug
Abstract

This TiCl 4-Mg promoted multicomponent coupling of various amides with CH(2)Cl(2) and methyl acrylate represents an extremely simple and practical synthesis of 1,5-keto esters. The efficiency of this chemistry is illustrated by the very simple preparation of unusual 4,4-dideuterio-1,5-keto esters.

Published
2008
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