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An abstract of the article "The Copper-Catalyzed Suzuki-Miyaura Coupling of Alkylboron Reagents: Disproportionation of Anionic (Alkyl)( (alkoxy)borates to Anionic Dialkylborates Prior to Transmetalation" by P. Basnet, S. Thapa and colleagues is presented.

The title reaction is achieved in the presence of a typical iridium photocatalyst and various substrates are tolerable. [ABSTRACT FROM AUTHOR]

The reaction has a broad substrate scope and tolerates diverse functional groups. [ABSTRACT FROM AUTHOR]

Following a scalable procedure alkyl chlorides equipped with a quinoline amide directing group are cross-coupled with various terminal alkynes to afford internal alkynes in high yields. [ABSTRACT FROM AUTHOR]

An abstract of the study "Iron-Mediated Inter- and Intramolecular Reductive Cross-Coupling of Unactivated Alkyl Chlorides With Aryl Bromides" by Z. Li and colleagues is presented.

Fully substituted stereocenters are highly enantioselectively generated by photoinduced copper-catalyzed coupling of readily available racemic tertiary alkyl chloride electrophiles with various amines. [ABSTRACT FROM AUTHOR]

An abstract of the article "Regioselective Synthesis of Carbonyl-Containing Alkyl Chlorides via Silver-Catalyzed Ring-Opening Chlorination of Cycloalkanols" by Feng-Qing Huang and colleagues is presented.

An abstract of the article "Photoinduced, Copper-Catalyzed Carbon-Carbon Bond Formation with Alkyl Electrophiles: Cyanation of Unactivated Secondary Alkyl Chlorides at Room Temperature" by Tanvi S. Ratani is presented.

The reaction fails for trifluoromethylated tertiary alkyl bromides and gives only poor yields for trifluoromethylated primary alkyl chlorides (not shown). [ABSTRACT FROM AUTHOR]

The lithium dispersion reductive lithiation of phenyl thioethers, alkyl chlorides, acrolein diethyl acetal, and isochroman is investigated. [ABSTRACT FROM AUTHOR]

The reaction succeeds using a 2-pyridyl group as the directing group, but is delivered with low or no yield when switching to a pyrazole or imine group. [ABSTRACT FROM AUTHOR]

The general and conceptually new method gives access to a broad variety of polychloro-substituted pyrrolidin-2-ones and indeno[2,1-c]pyrrol-3(3aH)-ones in moderate to good yields and high relative diastereoselectivities. [ABSTRACT FROM AUTHOR]

A one-pot three-component reaction between alkyl chlorides, sodium azide and terminal alkynes is also reported. [ABSTRACT FROM AUTHOR]

The first example of Rh-catalyzed borylation of unactivated alkyl chlorides is given. [ABSTRACT FROM AUTHOR]

Additionally an analog with a longer alkyl chain is synthesized. [ABSTRACT FROM AUTHOR]

The title reaction proceeds under ambient temperature and low catalyst loading with excellent chemo- and site-selectivities for a broad substrate scope. [ABSTRACT FROM AUTHOR]