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This study focuses on the neodymium isotopic composition (εNd) of mixed planktonic foraminifera species in sediment cores collected on the north-western margin of the South China Sea (SCS) and in the western equatorial Pacific. The aim was to identify temporal changes in the εNd of the Upper Circumpolar Deep Water (UCDW) during its northward penetration in the western subtropical Pacific and to re-evaluate the significance of deep-water εNd changes at the northern margin of the SCS over the past 25 kyr. The past seawater εNd record derived from sediments of the subtropical western Pacific displays a narrow range from − 2.9 ± 0.3 to − 1.6 ± 0.4. This suggests that the εNd of the UCDW is greatly modified during its northward penetration through the process of boundary exchange along the western volcanic margin of the South Pacific and that the unradiogenic εNd signature of the UCDW observed in the South Pacific (about − 6) has not been propagated beyond the equatorial Pacific, at least not over the last 25 kyr. Seawater εNd values obtained from the northern SCS display large variations with values that are lower (− 6.8 ± 0.3 to − 5.6 ± 0.2) for the last glacial period than for the late Holocene (− 5.7 ± 0.3 to − 4.1 ± 0.2). Such glacial εNd cannot be attributed to a higher proportion of southern-sourced water (SSW) as εNd values of the UCDW in the equatorial western Pacific are more radiogenic than those observed in the SCS. The evolution of the seawater εNd values of the northern SCS during the last glacial period and the last climatic transition is coeval with variations in the contribution of sediments from the Pearl River. The low sea level stand of the last glacial period resulted in a more proximal position of the Pearl River mouth relative to core MD05-2904, which a higher input of freshwater and, in particular, detrital sedimentary particles originating from the Pearl River that partially dissolved during sinking led to a decrease in the seawater εNd along the north-western margin of the SCS. Enhanced rainfalls associated with intensified monsoon and more frequent typhoon activities during the early Holocene Climatic Optimum (from 9 to 7 cal kyr BP) are linked to a decrease in sea surface salinity (lower δ 18 O values of planktonic foraminifera) and a decrease in εNd values (− 6.2 ± 0.3) induced by lithogenic Nd input from pronounced freshwater and sediment discharge from distal rivers. [ABSTRACT FROM AUTHOR]

Abstract: For the first time, modeling of the neodymium (Nd) isotopic composition (expressed as ε Nd) is performed in an Ocean Global Circulation Model (OPA-ORCA2.0 model). In the interest of simplicity, Nd concentration is not explicitly included and ε Nd is modeled as a passive tracer. Recent studies suggest that dissolved/particulate exchanges between continental margin sediments and seawater (termed boundary exchange, BE), could be the dominant source-sink terms that determine the distribution of neodymium isotopes in the global ocean. To test this hypothesis, we only included this BE source-sink term in the model. BE was parameterized as a relaxing term that forces ε Nd of seawater to the isotopic composition of the continental margin over a characteristic exchange time. Sensitivity tests were made using different exchange times and parameterizations. The model reproduces most of the general trends of ε Nd composition in seawater at global scale (inter-basin gradient, composition of some of the main water masses). These results suggest that BE process may account for the major sources and sinks of oceanic Nd, while indicating that the characteristic time of interaction between seawater and margins varies from about half a year in surface waters to several years at depth. The disparities between the model and observations might reflect the typical shortcomings of utilizing a coarse resolution ocean model circulation fields or neglected sources of neodymium such as dissolution of aeolian inputs or dissolved river loads. [Copyright &y& Elsevier]