1. Facile synthesis of protonated g-C3N4 and acid-activated montmorillonite composite with efficient adsorption capacity for PO43− and Pb(II).
- Author
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Wan, Xia, Khan, Muhammad Asim, Wang, Fengyun, Xia, Mingzhu, Lei, Wu, Zhu, Sidi, Fu, Chenlu, and Ding, Yong
- Subjects
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ADSORPTION capacity , *ADSORPTION isotherms , *ZETA potential , *POLLUTANTS , *METALLOTHIONEIN , *ADSORBATES , *MONTMORILLONITE - Abstract
• Protonated graphite carbon nitride and acid activated montmorillonite (g-C 3 N 4 /Mt). • Batch experiments carried out at various conditions i.e. adsorbate concentration, pH, temperature, and contact time. • 2%-g-C3N4/Mt showed enhanced adsorption capacity for PO 4 3− and Pb(II), 5.06 mg/g and 182.7 mg/g respectively. • The adsorption process for both contaminants showed well-fitting with the pseudo-second-order kinetic model. • The thermodynamic study suggested that the adsorption of Pb(II) was a spontaneous and endothermic process. A novel protonated graphite carbon nitride and acid-activated montmorillonite (g-C 3 N 4 /Mt) composite was prepared and evaluated its removal efficiency for PO 4 3− and Pb(II) from aqueous media. The as-prepared composite was characterized by XRD, FT-IR, TG, XPS, SEM, BET and Zeta potential. Batch experiments were carried out under various conditions such as the amount of adsorbent, initial adsorbate concentration (C o), solution pH, temperature, and contact time. 2.0%-g-C 3 N 4 /Mt presented maximum adsorption capacity for PO 4 3− and Pb(II) as compared to single g-C 3 N 4 , Mt or other synthesized composites. The removal efficiency of the as-prepared composite (2.0%-g-C 3 N 4 /Mt) was significantly elevated owing to the synergistic effects and the saturated adsorption capacities of PO 4 3− and Pb(II) on 2%-g-C3N4/Mt was 5.06 mg/g and 182.7 mg/g respectively. While the saturated adsorption capacity of bare g-C 3 N 4 was only 1.56 mg/g and 22.3 mg/g for PO 4 3− and Pb(II) respectively, and bare Mt showed adsorption capacity of 0.65 mg/g and 124.2 mg/g for PO 4 3− and Pb(II) respectively. The adsorption process for both contaminants showed well-fitting with the pseudo-second-order kinetic model, and the adsorption isotherm for both contaminants followed the Langmuir model. The thermodynamic study suggested that the adsorption of Pb(II) was a spontaneous and endothermic process. [ABSTRACT FROM AUTHOR]
- Published
- 2019
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