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[Display omitted] • Phase equilibria of CO 2 + DIOX hydrate for C DIOX between 0.05 mol% and 5.56 mol% • The kinetics of CO 2 + DIOX hydrate is quantified with morphology observation. • Phase separation of DIOX/H 2 O above 3.1 MPa weakens the promotion effect of DIOX. • A comprehensive evaluation of DIOX in the application of hydrate-based CO 2 storage. To reduce anthropogenic CO 2 emissions for the mitigation of climate change require novel CCUS solutions. Hydrate-based CO 2 sequestration (HCS) is a novel carbon-neutrality technology that aims to store CO 2 in solid hydrate form with long-term stability. However, imminent issues exist for the application of HCS in terms of demanding thermodynamic conditions, slow formation kinetics, and low CO 2 gas uptake. These challenges necessitate the quest for an efficient and eco-friendly CO 2 hydrate promoter. In this study, 1,3-dioxolane (DIOX) as a low-toxicity CO 2 hydrate promoter was systematically examined. The phase equilibria, cage occupancy, and the kinetics of binary CO 2 + DIOX hydrate were measured for DIOX concentrations (C DIOX) varying from 0.05 mol% to 5.56 mol%. It was confirmed that DIOX is a dual-function promoter for CO 2 hydrate, but its promotion effect is weakened for C DIOX between 0.60 mol% and 1.00 mol% and for all C DIOX at relatively high pressure. The CO 2 uptake in the hydrate phase increases with C DIOX above 2.00 mol% and is the highest for C DIOX = 5.56 mol% (57.08 ± 6.39 mmol/mol). Based on the morphology observation, hydrate transits from ice-like to slurry to mushy-like and finally to snow-like with increasing C DIOX. Interestingly, we observed that the aqueous phase separates into two phases (i.e., DIOX-rich and H 2 O-rich) at pressure above 3.09 MPa, which explains the gradual loss of the promotion effect. The results of our study provide a comprehensive evaluation on DIOX as a possible promoter for CO 2 hydrate in HCS application. [ABSTRACT FROM AUTHOR]

[Display omitted] Mitigation of climate change by reducing the anthropogenic CO 2 emissions has recently gained huge momentum. A prime pathway to achieve it in the short-medium term lies within capturing CO 2 from industries' flue gases. Post-combustion CO 2 capture (PCC) is the most mature methodology for large-scale CO 2 capture and closest to market. However, the conventional chemical absorption-based PCC process implies high regeneration energy requirements, constituting the majority of the energy load when adding PCC to the plant from which the CO 2 is going to be captured. As such, reducing the overall parasitic load of the conventional process is of interest. Changing the solvent or improving the process flowsheet are two main methodologies to achieve higher energetic efficiency and lower exergy losses. As there are several reviews dealing with novel solvents, this review critically evaluates the progress in improving the conventional PCC process through modifications of process configurations and shadowed by solvent replacements as drop-in solutions. The process configurations were grouped into absorption and stripping enhancement categories. A comparative analysis was conducted between the different available schemes in the literature and interactions between solvents and process configurations were showcased, highlighting the advantages and shortcomings of some of them. The review reveals the need for standardized framework and optimization algorithms using exergo-economic performance indicators for integrated solvent and process synthesis. [ABSTRACT FROM AUTHOR]