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1. Reactions of iridium hydride pincer complexes with dioxygen: new dioxygen complexes and reversible O2 binding.

Author

Bridget Williams D, Kaminsky W, Mayer JM, and Goldberg KI

Abstract

The reaction of molecular oxygen with iridium pincer hydride complexes, ((tBu)PCP)Ir(H)(X) [(tBu)PCP = kappa(3)-C(6)H(3)(CH(2)P(t)Bu(2))(2), X = Ph, H, CCPh], results in O(2) induced reductive elimination and formation of the novel dioxygen complexes ((tBu)PCP)Ir(O(2))(n) [n = 1 (), 2 ()].

Published
2008
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