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1. Efficient conversion of alkenes to chlorohydrins by a Ru-based artificial enzyme.

Author

Lopez S, Rondot L, Cavazza C, Iannello M, Boeri-Erba E, Burzlaff N, Strinitz F, Jorge-Robin A, Marchi-Delapierre C, and Ménage S

Subjects
Catalysis, Coordination Complexes chemistry, Molecular Conformation, Spectroscopy, Fourier Transform Infrared, Stereoisomerism, Alkenes chemistry, Chlorohydrins chemistry, Ruthenium chemistry
Abstract

Artificial enzymes are required to catalyse non-natural reactions. Here, a hybrid catalyst was developed by embedding a novel Ru complex in the transport protein NikA. The protein scaffold activates the bound Ru complex to produce a catalyst with high regio- and stereo-selectivity. The hybrid efficiently and stably produced α-hydroxy-β-chloro chlorohydrins from alkenes (up to 180 TON with a TOF of 1050 h -1 ).

Published
2017
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